Derivation of the atomic form factor

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SUMMARY

The atomic form factor is defined by the integral expression ∫ dV n_{j}(\vec{r})e^{-i \vec{G} \bullet \vec{r}}, where n(r) represents the electron density of the jth atom and G is the reciprocal lattice vector. The transition from the first equation to the second, 2 \pi ∫ dr r^{2} d(cos \alpha) n_{j}(r) e^{-iGr cos \alpha}, occurs under the assumption of spherical symmetry in the electron distribution. The notation d(cos \alpha) is clarified through integration in spherical coordinates, where the volume element is dV=r^2 sin(theta) dr d(theta) d(phi), and the integration limits for d(cos) range from -1 to 1.

PREREQUISITES
  • Understanding of atomic form factors in crystallography
  • Familiarity with spherical coordinates and their volume elements
  • Knowledge of reciprocal lattice vectors
  • Basic proficiency in calculus, particularly integration techniques
NEXT STEPS
  • Study the derivation of atomic form factors in crystallography
  • Learn about spherical coordinate transformations and their applications
  • Explore the concept of reciprocal lattice vectors in solid-state physics
  • Review integration techniques in multiple dimensions, focusing on spherical coordinates
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Physicists, materials scientists, and students studying crystallography or solid-state physics will benefit from this discussion, particularly those interested in the mathematical foundations of atomic form factors and spherical coordinates.

mjordan2nd
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My book defines the atomic form factor as

\int dV n_{j}(\vec{r})e^{-i \vec{G} \bullet \vec{r}}.

where n(r) is the electron density of the jth atom at r, and G is the reciprocal lattice vector. It says the above expression is equal to

2 \pi \int dr r^{2} d(cos \alpha) n_{j}(r) e^{-iGr cos \alpha}

in the case that the electron distribution is spherically symmetric where alpha is the angle between the reciprocal lattice vector and r. I don't understand how the author goes from the first equation to the second. In fact, I'm not sure I'm comfortable with this d(cos) notation at all. If someone could point me to a site where I could read up about that, I would appreciate it. The author then proceeds to integrate d(cos) from -1 to 1. Why he does this is unclear to me as well. Any help is appreciated.
 
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The integral is done in spherical coordinates.
The z axis is taken along the direction of the G vector so the angle between r and G si theta (the polar angle).
The volum element in spherical coordinates is
dV=r^2 sin(theta) dr d(theta) d(phi)
The author writes sin(theta)d(theta) as d(cos theta).
n(r) is asumed to have spherical symmetry here so it depends on the r (magnitude, not vector) only.

For more on sperical coordinates, you can see this, for example:
http://en.wikipedia.org/wiki/Spherical_coordinate_system
 

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