Why is My Lattice Energy Calculation for PbCl2 Different from the Book's?

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SUMMARY

The discussion centers on the discrepancy in lattice energy calculations for lead(II) chloride (PbCl2) using Hess's Law. The user initially calculated a value of -1770 kJ but noted the correct value should be -2484 kJ. The error identified was the failure to flip the sign for the reaction 2Cl(g) → Cl2(g). Despite this correction, the user still could not reconcile their result with the book's value, suggesting potential inaccuracies in the textbook.

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cuallito
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Homework Statement
Determine the lattice energy of PbCl2
Relevant Equations
Lattice energy= Heat of formation- Heat of atomization- Dissociation energy- (sum of Ionization energies)- (sum of Electron Affinities)
Here's my attempt at solving it using Hess's Law. I get -1770kJ when I add up all the numbers. The correct answer is supposed to be -2484 kJ.

lattice energy.png
 
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I forgot to flip the sign for 2Cl(g)->Cl2(g), but I'm still not getting the right number:
1637001678311.png
 
I agree with your calculation. Maybe the book's wrong - it happens.
 
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