Diamond oxidation -- covalent bonds

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    Bonds Oxidation
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Discussion Overview

The discussion centers on the oxidation of diamond, specifically whether covalent bonds must be broken for this process to occur and the implications of heating diamond in an oven at 150 degrees Celsius. Participants explore the theoretical aspects of the reaction, including activation energy and reaction rates.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant questions if covalent bonds need to be broken for diamond oxidation to occur.
  • Another participant asserts that diamond oxidizes to CO2 when heated in air, although they are uncertain if 150°C is sufficient for this reaction.
  • A third participant references a study indicating that the activation energy for diamond oxidation is 220 kJ/mol and calculates that at 140°C, the reaction would take an extraordinarily long time (480 million years) to occur, expressing uncertainty about their reasoning.
  • Subsequent comments clarify that the calculated time may not represent when the reaction starts but rather when observable effects might be noted, suggesting a need for further clarification on the definition of characteristic time.
  • Participants humorously note that the effectiveness of the reaction depends on how long one is willing to wait.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the sufficiency of 150°C for diamond oxidation, and there are differing interpretations of the calculated reaction time and its implications.

Contextual Notes

The discussion includes assumptions about the definitions of reaction times and the conditions under which oxidation occurs, which remain unresolved.

PatrickP2
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In order for a diamond to oxidize, do the covalent bonds have to be broken? What would happen if I put the diamond in an oven heated to 150 degrees celsius? Would the reaction start and after some time the stone would disappear?
 
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No idea if 150°C will be enough, but yes, diamond heated in the air oxidizes to CO2.
 
I did a little research and found a study on the oxidation of diamond. It shows that the activation energy is 220 kJ/mol, while the pre-exponential factor is 4.3×10^11 per second. I used the Arrhenius equation and calculated that at 140 C the reaction would take place after 480 million years. I don't know if my reasoning is right, because I have little to do with chemistry and physics, but it seems that 140 C in the oven is not enough after all. :D

Here's the equation I used:
https://www.wolframalpha.com/input?...iusEquation",+"A1"}+->"4.3×10^11++per+second"
 
PatrickP2 said:
the reaction would take place after 480 million years

No idea how they define the characteristic time, typically it would be something like half life, so it is not like "reaction takes place after", more like "after comparable time effects of the reaction are obvious".

PatrickP2 said:
it seems that 140 C in the oven is not enough after all. :D

Obviously depends on how long you can wait :wink:
 
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