Discrete Spectrum Non-Degeneracy in 1D: How to Prove?

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SUMMARY

The discussion centers on proving the non-degeneracy of states corresponding to the discrete spectrum in one-dimensional quantum systems. The key equation referenced is the time-independent Schrödinger equation, represented as \(\hat{H}\psi_n=E_n\psi_n\). The example of the 1D square well is highlighted, where energy levels are given by \(E = \frac{n^2\pi^2\hbar^2}{2ma^2}\), demonstrating non-degenerate eigenvalues. The challenge lies in generalizing this proof beyond specific cases.

PREREQUISITES
  • Understanding of quantum mechanics principles, particularly the Schrödinger equation.
  • Familiarity with discrete spectra and eigenvalue problems in quantum systems.
  • Knowledge of one-dimensional potential wells, specifically the 1D square well model.
  • Basic grasp of linear algebra concepts related to eigenfunctions and eigenvalues.
NEXT STEPS
  • Study the proof techniques for eigenvalue uniqueness in quantum mechanics.
  • Explore the implications of the spectral theorem in quantum systems.
  • Investigate the mathematical properties of Hermitian operators in quantum mechanics.
  • Learn about perturbation theory and its effects on degeneracy in quantum states.
USEFUL FOR

Students of quantum mechanics, physicists focusing on quantum systems, and educators teaching concepts of discrete spectra and eigenvalue problems.

andre220
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Homework Statement



Prove that in the 1D case all states corresponding to the discrete spectrum are non-degenerate.

Homework Equations



[tex]\hat{H}\psi_n=E_n\psi_n[/tex]

The Attempt at a Solution



Okay so, what I am stuck on here is that the question is quite broad. I can think of specific cases like the 1D square-well where [itex]E = \frac{n^2\pi^2\hbar^2}{2ma^2}[/itex] which is non-degenerate. But in a more general sense this does not seem so easy to prove. We do know that the eigenvalues in this case are discrete ([itex]E_n[/itex]) and the eigenfunctions are [itex]\psi_n[/itex], however I do not know where to go from here.
 
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So basically what you want to prove is that if ##\hat{H}(\psi_n-\psi_m)=0##, then ...
 

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