Dissociation of Acids & Bases into Ions

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SUMMARY

Acids and bases dissociate into ions in water due to the polar nature of water molecules, which creates stronger ionic attractions with the dissolved ions than the original bonds in the compounds. According to Arrhenius' definition, acids and bases are specifically substances that dissociate in water to produce H+ or OH- ions. This phenomenon is not exclusive to acids and bases; other ionic compounds, such as NaCl, also dissociate in water. The key factor driving this dissociation is the interaction between the polarized water molecules and the ionic bonds of the solutes.

PREREQUISITES
  • Understanding of Arrhenius theory of acids and bases
  • Knowledge of ionic and covalent bonding
  • Familiarity with the properties of polar solvents
  • Basic concepts of solubility and dissociation in chemistry
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  • Research the role of polar solvents in solvation processes
  • Study the dissociation of various ionic compounds in water
  • Explore the implications of ionic strength on chemical reactions
  • Learn about the properties of water as a solvent in biological systems
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Chemistry students, educators, and professionals interested in the behavior of acids, bases, and ionic compounds in aqueous solutions.

labinojha
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why do acids and bases dissociate into ions while in water?
 
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It's not just acids and bases...other compounds do it too (ex. NaCl). Look at how they dissociate and which ions are found once they do. Specifically, look at the type of bond between the two ions (hint). What type of solvent is water and how might this play a role?
 
Generally because water molecules are polar. The ionic attraction between the polarized water molecules and the dissolved atoms are stronger than the bonds in the original molecules.
 
This is a little bit putting things on the head. By (Arrhenius) definition acids and bases are substances that dissociate in water producing either H+ or OH-. As dissociation is part of the definition, every substance that we classified as acid or base must be dissociating. In effect answer to the question "why those substances dissociate" is "because we have chosen substances that dissociate".
 

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