Does electricity have an effect in reactivity?

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sciman
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hello

I wonder if electrifying a metal will increase its reactivity with other substances or not

the mechanism I imagine it to be the increased movement of valence electrons, perhaps an energy excitation of them, so that they react more with substrate

is this true?

thanks
 
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mmm, true, but in electrolysis the metal doesn't act like catalyst
it doesn't react with the substrate, it just poses an electrical field, under which the substrate separates in its parts
 
Electroplating, electroforming, electrodeposition