I could imagine a couple different reasons why this would happen.
1) How does the steam get heated? If heated by a constant heat flux device such as an electric heater, then a decrease in flow rate will increase the temperature coming out of your heater. Note that an electric heater will simply get hotter as you decrease flow rate, making your steam hotter.
2) Another possibility is there's thermal mass in your system between the steam source and plastic sintering processes that gets hotter over time, absorbing heat from the steam so that eventually the temperature comes to some thermal equilibrium but perhaps during this process you're referring to you don't quite get to thermal equilibrium and your steam gradually gets hotter.
Perhaps you should explain a bit more about your process, especially upstream of the plastic where you're creating and heating the steam. I don't see any way a decrease in flow rate should otherwise cause an increase in the inlet temperature if inlet pressure remains constant. That seems to indicate that you're boiling water at some steady pressure and superheating it afterwards.