Folks,
Zigzag transformers are used all over the world for earthing (grounding) and unearthed bus, and in voltage ranges from LV to MV. I think the original question is along the lines "why would you bother earthing a bus with a separate zigzag when star-points (wye-point) are available?" I think it mainly comes down to cost - if there is a need to Earth a bus via several separate star-connected transformers, each with associated neutral bushing and full voltage insulation at the netra end, the lower cost with a single zigzag transformer comes into consideration. I have seen them on a set of 33 kV busses where one of the incomers was delta, so there was a possibility of an ungrounded bus if that incomer was in service with all other star-connected feeders and incomers out of service - a dedicated earthing transformer then makes sense and zigzag construction is a very cost-effective way of achieving that. If all incomers on a bus were star connected and are able to be earthed at tehe star-point, then there is no need for a separate earthing transformer.
Earthing transformers do not have to be zigzag - it is just one method - they can also be a more normal star delta with the star-point earthed and the delta either used for aux power or not used.