Easiest way to find out if oxygen is produced

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Discussion Overview

The discussion revolves around methods to determine if oxygen is produced in a chemical reaction, explicitly excluding combustion reactions. Participants explore various experimental approaches and theoretical considerations related to oxygen detection.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant suggests exposing gas to iron in the presence of water to observe rust formation as an indication of oxygen presence.
  • Another participant mentions the blue bottle experiment, where NaOH oxidizes glucose and the presence of oxygen can be inferred from the reoxidation of methylene blue.
  • A different approach is proposed involving trapping oxygen and exposing it to hot copper metal to form copper oxide, referencing historical methods used by Lord Rayleigh for nitrogen composition analysis.
  • Additional methods are hinted at, including quantum and thermodynamic analyses, instrumental detection techniques, and electrolysis or galvanic methods under high partial pressure of oxygen.

Areas of Agreement / Disagreement

Participants present multiple competing methods for detecting oxygen, and there is no consensus on a single easiest method. The discussion remains unresolved with various viewpoints and suggestions offered.

Contextual Notes

Some methods mentioned depend on specific conditions, such as the inert atmosphere for rusting or the assumptions made in historical analyses. The discussion does not clarify the effectiveness or practicality of all proposed methods.

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What is the easiest way you can tell or find out if oxygen is produced in a certain reaction? Or in other words, how can one prove that a certain reaction releases oxygen? The answer cannot deal with combustion.


I searched on google, and couldn't quite get an answer. I thought about it for a while, but simply cannot think of anything.

Any help will be appreciated.
 
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You could expose the gas to iron in the presence of water and see if it rusts. If there isn't any oxygen then you won't get rust. You'd have to keep the iron under an otherwise inert atmosphere.
 
NaOH can oxidize glucose and reduce methylene blue, forming a colorless solution. Oxygen, however, can reoxidize the solution returning the blue color.

Look up the blue bottle experiment.
 
can we simply use growing sprint?
 
What is the easiest way you can tell or find out if oxygen is produced in a certain reaction? Or in other words, how can one prove that a certain reaction releases oxygen? The answer cannot deal with combustion.


I searched on google, and couldn't quite get an answer. I thought about it for a while, but simply cannot think of anything.

Any help will be appreciated.

In addition to what everyone contributed to. Assuming that only oxygen is released you can trap the oxygen (or air flow rather) and expose it to hot copper metal, you'll have the formation of copper oxide and you can perform a gravimetric analysis. Lord Rayleigh employed the method to compare the nitrogen composition in air (assuming oxygen and nitrogen gas constituents) with that obtained through decomposition of nitrogen compounds; he removed the oxygen from air and compared the mass of the nitrogen for a given volume (from the resulting density) from the mass obtained from the latter method. Statistical measures revealed a discrepancy between the two replicate measurements...the mass from air was slightly higher, this was due to the slight prescence of Argon, for which he detected and won the Nobel prize.

I'm sure there are other practical methods for detection, some may involve a peculiar quantum, thermodynamic (rate analysis involving ozone), and physical characteristic of oxygen; such as those involved in instrumental detectors. Or perhaps a certain electrolysis or galvanic method (galvanic method or electrolysis with a high partial pressure of oxygen for qualitative analysis). Oxygen is also a good quencher, so you may want to refer to what Cesium mentioned.

I'm sure there are standard methods, nothings springs to mind at the moment.
 

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