Effect of pressure on hydrogen spectrum

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SUMMARY

The discussion focuses on the relationship between hydrogen gas pressure and the intensity of its spectral lines. It is established that high pressure, when coupled with high temperature, leads to high energy transitions resulting in more intense ultraviolet emissions. Conversely, high pressure at room temperature does not produce significant high energy transitions, as indicated by the Boltzmann factor. The need for a chart illustrating these relationships is also highlighted.

PREREQUISITES
  • Understanding of hydrogen spectral lines and their intensity
  • Knowledge of gas laws and pressure-temperature relationships
  • Familiarity with the Boltzmann factor in statistical mechanics
  • Basic principles of spectroscopy
NEXT STEPS
  • Research the effects of pressure on hydrogen spectral lines using spectroscopy tools
  • Explore the Boltzmann distribution and its implications for gas transitions
  • Investigate high-pressure gas behavior at varying temperatures
  • Find or create charts that correlate pressure and spectral line intensity for hydrogen
USEFUL FOR

Physicists, chemists, and students studying spectroscopy, particularly those interested in the effects of pressure and temperature on gas emissions.

zincshow
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I am interested in finding and understanding the relationship between the hydrogen spectrum (which of the lines are more intense) and the pressure that the hydrogen gas is under. Does hi-pressure gas mean lots of ultraviolet or hardly any? Is there a chart somewhere?

TIA
 
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zincshow said:
I am interested in finding and understanding the relationship between the hydrogen spectrum (which of the lines are more intense) and the pressure that the hydrogen gas is under. Does hi-pressure gas mean lots of ultraviolet or hardly any? Is there a chart somewhere?

TIA
Hi,

I can hardly imagine hi-pressure without high temperature though it is possible. The fact is that if your hi-pressure is related to high temperatures then you will have high energy transitions. However if you have high pressure with room temperature I don't think (i have the Boltzmann factor in mind) that you will have such high energy transitions...
 

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