Electrolytic vs. electrochemical vs. galvanic cells.

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Discussion Overview

The discussion focuses on the differences between electrolytic, electrochemical, and galvanic cells, exploring their definitions, functions, and classifications. Participants express confusion regarding the relationships and characteristics of these cell types.

Discussion Character

  • Conceptual clarification, Debate/contested

Main Points Raised

  • Some participants assert that electrolytic cells are nonspontaneous and require external energy to function, while galvanic cells are spontaneous and do not need external energy.
  • One participant questions whether galvanic cells are a distinct type of cell or simply a category within electrochemical cells.
  • Another participant clarifies that both electrolytic and galvanic cells fall under the broader category of electrochemical cells.
  • It is noted that in electrolytic cells, electrical energy is converted to chemical energy, whereas in galvanic cells, chemical energy is converted to electrical energy.

Areas of Agreement / Disagreement

Participants generally agree on the basic definitions and functions of electrolytic and galvanic cells, but there is some uncertainty regarding their classifications and the implications of their differences.

Contextual Notes

Some participants express confusion about the charge of anodes and cathodes, indicating a potential gap in understanding that may affect their interpretations of the cell types.

Drteeth
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So my question is what is the difference between these cells? This always confuses me. I know that electrolytic cells are nonspontaneous and that their cathode is negative which means that electrons are going against their gradients here. I am also aware of the fact that a galvanic cells is spontaneous and that the cathode is positive, however, I was unsure if this is its own cell type or is it a type of electrochemical cell?

Thanks for clearing this confusion up for me!
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Drteeth, you just answered your own question. What confuses you?
Electrolytic - The reaction needs energy to be put into the system from external source; otherwise the reaction does not happen.
Galvanic - the reaction happens because it WANTS to happen; no energy needs to be supplied from the outside.
 
**** ... i forgot that the anodes/cathodes are different charges, i was asked a bunch of questions on that on my final. eek!
 
Ok, I think I figured this out - both electrolytic and galvanic cells are electrochemical cells. It was really just the classifications that I wasnt getting...

Thanks for the help...
 
Last edited:
In electrolytic cell, electrical energy is converted to chemical energy where as in galvanic cell, chemical energy is converted to electrical energy.
 

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