-ene Nomenclature (semi-structural formulas)

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SUMMARY

The discussion centers on the nomenclature of semi-structural formulas for alkenes (-ene) and alkynes (-yne), specifically addressing the representation of double bonds. The equal sign (=) in formulas such as CH3CH2CH=CH2 indicates the presence and location of a double bond. While CH2=CH2 is a correct representation for ethene, CH2CH2 is often used informally to denote the same structure without explicitly showing the double bond. It is recommended to use proper structural diagrams for formal representations.

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  • Knowledge of alkenes and alkynes
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Rudders
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Hi,

I was just confused as to the semi-structural formula nomenclature of -ene and -yne structures. The thing that I don't understand is the = sign in the formula.

For example:
CH3CH2CH=CH2

What does that equals sign mean? Does it represent where the double bond is located?

If so, why does ethene have the structural formula CH2CH2 instead of CH2=CH2

Thanks
-Rudders
 
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Rudders said:
What does that equals sign mean? Does it represent where the double bond is located?
Yes.

If so, why does ethene have the structural formula CH2CH2 instead of CH2=CH2

You can write it both ways. CH2CH2 is the 'normal' way, whereas when you use an equal sign to represent the double bond you're approximating the structure diagram in text. Formally you should really stick to either the formula or a full and proper structure diagram, but in informal contexts it can be useful.
 

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