Energy levels of a 3 dimensional infinite square well

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Homework Help Overview

The discussion revolves around calculating the wavelength of electromagnetic radiation emitted during an electron transition between energy levels in a three-dimensional infinite square well. The focus is on understanding the energy level equations and the specific quantum numbers associated with these levels.

Discussion Character

  • Conceptual clarification, Assumption checking

Approaches and Questions Raised

  • The original poster attempts to clarify the quantum numbers for the third energy level, questioning whether they should be (1, 2, 2) for E3. Some participants confirm this interpretation and discuss the implications of degeneracy in energy levels.

Discussion Status

The discussion is progressing with participants confirming the original poster's understanding of the energy levels. There is a suggestion to explore rectangular/square wells further to enhance comprehension.

Contextual Notes

Participants note the importance of distinguishing between the third energy level and the third excited state, as well as the implications of degeneracy in the context of the problem.

bobred
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Homework Statement



Calculate the wavelength of the electromagnetic radiation emitted when
an electron makes a transition from the third energy level, E3, to the lowest energy level, E1.

Homework Equations



E_n = \frac{\left (n_{x}^{2}+n_{y}^{2}+n_{z}^{2} \right) \pi^{2} \hbar^{2}}{2m_{e}L^{2}}

The Attempt at a Solution


Working out the wavelength is not a problem, my problem comes for the values of n for the third level. For the lowest energy level we have

(1^{2} + 1^{2} + 1^{2})

My question is for the third energy level is it

(1^{2} + 2^{2} + 2^{2})?

Thanks
 
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Yep, as long as they are referring to E3 and not the third excited state in the problem,(E1 is the ground state the way you asked the question). And for your interest you are dealing with a symmetric box so the energy levels are degenerate. Meaning you could take 2,2,1 1,2,2 or 2,1,2. E2 would be 2,1,1, 1,2,1 or 1,1,2. These are called degenerate eigenstates.
 
Thanks that's what I thought.
 
No problem, I recommend you look into rectangular/square wells to refine your understanding.
 
Last edited:

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