Energy values in infinite potential well

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SUMMARY

The energy values for a particle in an infinite potential well are defined by the equation E_{n} = \frac{\hbar^2 \pi^2 n^2}{8 m a^2}, demonstrating that energy E_{n} is proportional to the square of the quantum number n (E_{n} ∝ n²). This non-linear relationship results in increasing spacing between energy levels as n increases. The solution to the Schrödinger equation reveals that only discrete energy levels are permitted due to boundary conditions, with momentum p scaling linearly with n and energy scaling with the square of momentum.

PREREQUISITES
  • Understanding of quantum mechanics principles
  • Familiarity with the Schrödinger equation
  • Knowledge of energy quantization in potential wells
  • Basic grasp of wave-particle duality
NEXT STEPS
  • Study the implications of boundary conditions in quantum systems
  • Explore the concept of quantized energy levels in different potential wells
  • Learn about the mathematical derivation of the Schrödinger equation
  • Investigate the relationship between momentum and energy in quantum mechanics
USEFUL FOR

Students and professionals in physics, particularly those focusing on quantum mechanics, as well as educators seeking to explain energy quantization in potential wells.

phys2
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I was wondering why the spacing between energy values keep increasing for the infinite potential well?
 
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The energy equation for a particle inside an infinite square well is

[itex]E_{n}[/itex] = [itex]\frac{\hbar^2 \pi^2 n^2}{8 m a^2}[/itex]

So [itex]E_{n} \propto n^2[/itex]

So the relationship between energy and increasing n is non-linear.
 
phys2 said:
I was wondering why the spacing between energy values keep increasing for the infinite potential well?
The solution of the Schrödinger equation inside the square well is a plane wave identical to a free particle, but due to the boundary conditions only discrete levels n are allowed. The momentum p scales with n, i.e. p~n; the energy scales with p², so E=p²/2m~n².
 

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