Energy values in infinite potential well

In summary, the spacing between energy values in the infinite potential well increases non-linearly as n increases. This is due to the discrete levels allowed by the boundary conditions and the relationship between momentum and energy.
  • #1
phys2
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I was wondering why the spacing between energy values keep increasing for the infinite potential well?
 
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  • #2
The energy equation for a particle inside an infinite square well is

[itex]E_{n}[/itex] = [itex]\frac{\hbar^2 \pi^2 n^2}{8 m a^2}[/itex]

So [itex]E_{n} \propto n^2 [/itex]

So the relationship between energy and increasing n is non-linear.
 
  • #3
phys2 said:
I was wondering why the spacing between energy values keep increasing for the infinite potential well?
The solution of the Schrödinger equation inside the square well is a plane wave identical to a free particle, but due to the boundary conditions only discrete levels n are allowed. The momentum p scales with n, i.e. p~n; the energy scales with p², so E=p²/2m~n².
 

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