Entropy change of ice-water mixture at 273K

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SUMMARY

The discussion centers on calculating the entropy change of a system consisting of a mixture of 1.773 kg of water and 227 g of ice at 273K. The final equilibrium state is achieved when the water-ice mass ratio is 1:1. The correct calculation for the entropy change, using the heat of fusion of water at 334 J/g, results in an entropy change of -915 J/K, confirming the method's accuracy despite initial miscalculations.

PREREQUISITES
  • Understanding of thermodynamic principles, specifically entropy and heat transfer.
  • Familiarity with the concept of phase changes and the heat of fusion.
  • Knowledge of calculus for evaluating integrals in thermodynamic equations.
  • Proficiency in unit conversions, particularly between kilograms and grams.
NEXT STEPS
  • Study the derivation and application of the entropy formula, ΔS = ∫(dQ/T).
  • Learn about the heat of fusion and its implications in phase change calculations.
  • Explore advanced thermodynamic concepts, including reversible and irreversible processes.
  • Investigate the impact of temperature on entropy changes in different materials.
USEFUL FOR

This discussion is beneficial for students studying thermodynamics, particularly those focusing on entropy calculations, as well as educators and professionals in physics and engineering fields who require a solid understanding of phase transitions and energy transfer.

lowerlowerhk
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Homework Statement


A mixture of 1.773kg of water and 227g of ice is in an initial equilibrium state at 273K, in a reversible process, brought to a second equilibrium state where the water-ice ratio,by mass, is 1:1 at 273K. Calculate the entropy change of the system during the process.

Homework Equations


E=mL
\Delta S=\int\limits_{i}^{f}\frac{dQ}{T}
specific heat of fusion of water = 333000J/kgK

The Attempt at a Solution



Since final mass ratio is 1:1 the final mass is both ice and water is
m=(1.733+0.277)/2=1.025kg, which means 0.748 kg of water is turned to ice. Some water gives away energy and freezes to ice.
\Delta E=-0.748(333000)=-249084J
\Delta S=-249084/273=-912J/K
But that is not the answer.
 
Last edited:
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lowerlowerhk said:
Since final mass ratio is 1:1 the final mass is both ice and water is
m=(1.773+0.277)/2=1.025kg, which means 0.748 kg of water is turned to ice. Some water gives away energy and freezes to ice.
\Delta E=-0.748(333000)=-249084J
\Delta S=-249084/273=-912J/K
But that is not the answer.
Your method is correct. Use 334 J/g as the heat of fusion for water. I get -915 J/K

AM
 

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