Entropy in Chemistry: Questions and Answers

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SUMMARY

This discussion addresses two key questions regarding entropy in chemistry. First, it confirms that a spontaneous process can occur where the entropy of the surroundings decreases, specifically during heat transfer between objects. Second, it clarifies that a system is at equilibrium when the change in entropy of the system (ΔSsys) equals zero, not necessarily when ΔSsys equals ΔSsurr.

PREREQUISITES
  • Understanding of the second law of thermodynamics
  • Familiarity with concepts of entropy and spontaneous processes
  • Knowledge of thermodynamic equilibrium
  • Basic principles of heat transfer in physical chemistry
NEXT STEPS
  • Research examples of spontaneous processes with decreasing entropy in the surroundings
  • Study the second law of thermodynamics in detail
  • Learn about thermodynamic equilibrium conditions
  • Explore heat transfer mechanisms in thermodynamic systems
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Chemistry students, educators, and professionals interested in thermodynamics and entropy concepts.

ada0713
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I have two questions regaring my homework assignmnet

1) Is there a "spontaneous process" where the "entropy of the surrounding" decreases?
If so, what kind of reactions (or process) falls into this category? I was trying to
think of something but couldn't/

2) and this was is just to make sure I got it right.. Is it right that the system
is always at equilibrium when [delta S sys= delta S surr].. or do they all have
to euqal to zero?

thanks
 
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any help please?
 
1) Entropy is transferred when one object heats another. Can you think of an example when a system is heated by its surroundings?

2) The condition of system equilibrium is dSsys=0.
 

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