Equilibrium Constant: Multiplying Concentrations Explained

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SUMMARY

The discussion centers on the concept of the equilibrium constant (K) in chemical reactions, specifically defined for the reaction pA + qB ⇌ rC + sD as K = [C]^r [D]^s / [A]^p [B]^q. Participants clarify that the multiplication of concentrations in the equilibrium expression is based on the principle that the rate of reaction is proportional to the frequency of molecular collisions, which is directly related to the concentrations of the reactants and products. This foundational understanding is crucial for grasping chemical equilibrium dynamics.

PREREQUISITES
  • Understanding of chemical equilibrium concepts
  • Familiarity with the notation of chemical reactions
  • Basic knowledge of concentration and its measurement
  • Introduction to reaction kinetics
NEXT STEPS
  • Study the derivation of the equilibrium constant expression in detail
  • Explore the concept of reaction kinetics and collision theory
  • Learn about Le Chatelier's principle and its application to equilibrium
  • Investigate the impact of temperature and pressure on equilibrium constants
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Chemistry students, educators, and professionals seeking a deeper understanding of chemical equilibrium and reaction dynamics.

carrera901
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Hey all

I have trouble understanding something about the Equilibrium constant.

If you have this chemical equilibrium:

pA + qB \Leftrightarrow rC + sD

You can define the equilibrium constant with

[C]r [D]s
______ = K
[A]p q

I don't understand why you multiply the concentrations, can anyone explain?

I'm very sorry if this is a very dumb question and sorry for my english

And no idea why the arrow goes up :-P
 
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Use LaTeX

K = \frac {[A]^p<b>^q} {[C]^r[D]^s} </b>

I am not sure what you are asking about.

Are you asking why it is defined this way? Because it was defined this way :smile:

Are you asking why it works? That's a much better question. As a first approximation you may assume that's because to react molecules have to collide and amount of collisions is directly proportional to the concentration.

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