Express a wave function as a combination of spherical harmonics

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SUMMARY

The discussion focuses on expressing the wave function of an electron in a hydrogen atom, given by ψ(r,θ,φ)=R(r)[cos(θ)+eiφ(1+cos(θ))], as a linear combination of spherical harmonics Ylm. The key challenge is to find the appropriate coefficients for the spherical harmonics that correspond to the measurements of L² yielding 6ℏ² and Lz yielding ℏ. Participants suggest calculating the projection of the angular part onto the state |l m⟩ and experimenting with combinations of spherical harmonics to achieve the desired expression.

PREREQUISITES
  • Understanding of spherical harmonics Ylm
  • Familiarity with quantum mechanics concepts such as angular momentum operators L² and Lz
  • Knowledge of wave functions in quantum mechanics
  • Experience with normalization of wave functions
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  • Learn how to calculate projections of wave functions onto spherical harmonics
  • Study the properties and applications of spherical harmonics in quantum mechanics
  • Explore normalization techniques for wave functions in quantum systems
  • Investigate the implications of angular momentum measurements in quantum mechanics
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Students and professionals in quantum mechanics, particularly those studying atomic physics, wave functions, and angular momentum in quantum systems.

mat8845
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Homework Statement



An electron in a hydrogen atom is in a state described by the wave function:

ψ(r,θ,φ)=R(r)[cos(θ)+e(1+cos(θ))]

What is the probability that measurement of L2 will give 6ℏ2 and measurement of Lz will give ℏ?

Homework Equations



The spherical harmonics

The Attempt at a Solution



I know that I need to express the part in (θ,φ) as a linear combination of spherical harmonics. Then I would normalize my wave function, and the coefficients would lead me to the probability I need.

My problem is to express ψ in terms of the spherical harmonics Ylm. Is there a general method to do so? Thanks.
 
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The way I would do it is by looking at \mathbf{L}^2|l \mspace{8mu} m> = \hbar^2 l(l+1) |l\mspace{8mu} m> and \mathbf{L}_z |l \mspace{8mu}m> = \hbar m |l\mspace{8mu} m>. And looking at a table of spherical harmonics. There is no need to normalize them since they are already normalized.
 
mat8845 said:

Homework Statement



An electron in a hydrogen atom is in a state described by the wave function:

ψ(r,θ,φ)=R(r)[cos(θ)+e(1+cos(θ))]

What is the probability that measurement of L2 will give 6ℏ2 and measurement of Lz will give ℏ?

Homework Equations



The spherical harmonics

The Attempt at a Solution



I know that I need to express the part in (θ,φ) as a linear combination of spherical harmonics. Then I would normalize my wave function, and the coefficients would lead me to the probability I need.

My problem is to express ψ in terms of the spherical harmonics Ylm. Is there a general method to do so? Thanks.
You could find the projection of the angular part onto the state ##\vert l\ m \rangle## by calculating ##\langle l\ m \vert \psi\rangle##. Seems to be kind of a pain though. I'd just futz around with the spherical harmonics to find a linear combination that works. For example, the ##e^{i\phi}## part has to come from an m=1 state.
 

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