a few more remarks, gleaned from perusing works of experts:
a "connection" is a method of differentiating vector fields on manifolds in the direction of tangent vectors. this differentiation is called "covariant" differentiation, [and is denoted by some authors, such as Nomizu, with a del symbol]. The fundamental lemma of riemannian geometry says there is a unique "symmetric" connection which is compatible with a given metric.
Then the curvature can be defined as the extent to which the SECOND covariant derivative fails to be symmetric.
Thus there is a method if defining curvature entirely from the datum of a riemannian metric, i.e. dot product on each tangent space.
In shifrins notes above, the covariant derivative of a surface in three space is given a very simple definition, as ordinary differentiation in R^3, followed by orthogonal projection of the derivative onto the tangent space of the surface, using of course the induced metric from the embedding.
the curvature, unlike the connection it seems, behaves like a "tensor". Moreover curvature can be viewed locally as matrix of 2 forms, just as the connection can be viewed locally as a matrix of one forms.
Anyway, since matrices have various invariants, trace, determinant, etc... so also one can apply these invariant polynomials to the curvature matrices, obtaining globally meaningful objects called "characteristic classes". they are named after famous people like whitney, chern, pontrjagin, euler etc...
[example: at a given point of the surface, there are two mutually orthogonal length minimizing curves, called geodesics, with respectively largest and smallest curvature, i.e. approximable by circles with smallest and largest radii. the product of these two curvatures is called the gauss curvature at the point. locally the curvature form of an embedded surface in R^3, is the product of the gaussian curvature, with the standard oriented area form. the integral of the gaussian curvature over the manifold is the euler characteristic. (times 2pi or something).]
recall the euler class is the primordial characteristic class. the general fact, called the gauss bonnet chern theorem is perhaps that the top chern (characteristic) class equals the euler class.
References: milnor: morse theory pages 43-54, milnor - stasheff: chracteristic classes, appendix C.