Find thermodynamic generalized force

Click For Summary
The discussion focuses on calculating the work done on a microscopic pendulum modeled as a quantum harmonic oscillator, specifically when the pendulum's length varies by ##dl##. The partition function is derived as ##Z= \frac{1}{2sinh(\beta\hbar\omega/2)}##, where ##\epsilon_n = \hbar\omega(1/2 + n)## and ##\beta= \frac{1}{kT}##. The Helmholtz Free Energy is expressed as ##F = U - TS = -kT\ln{Z}##, leading to the internal energy relation ##U = F - T\frac{\partial F}{\partial T}##. A challenge arises in determining the thermodynamic generalized force since the dependence of thermodynamic variables on the length ##l## is unclear, particularly how ##\omega## varies with ##l##. The discussion highlights the complexity of linking microscopic properties to macroscopic thermodynamic forces.
damarkk
Messages
12
Reaction score
2
Homework Statement
Statistical Mechanics
Relevant Equations
Canonical Ensemble, Thermodynamic generalized forces
Assume you have a microscopic pendulum you can suppose is like quantum harmonic oscillator. If the length of pendulum has variation of ##dl##, calculate the work on the pendulum and thermodynamic generalized force.
Find also the variation of mean number of extitations.


My Attempt

Firstly, I find the partition function: ##Z= \sum_n e^{-\beta\epsilon_n}##, with ##\epsilon_n = \hbar\omega(1/2 + n)## and this is the result:

##Z= \frac{1}{2sinh(\beta\hbar\omega/2)}##.

In this result ##\beta= \frac{1}{kT}##.

Then, I can write Helmholtz Free Energy: ##F = U -TS = -kT\ln{Z}##

And of course ## U = F-T\frac{\partial F}{\partial T}##


I know that ##-\frac{\partial U}{\partial x} = F_x## but if i don't know how thermodynamic variables depends on ##l## how I can compute the thermodynamic generalized force?
 
Physics news on Phys.org
##\omega## depends on l.
 
(a) The polarisation pattern is elliptical with maximum (1,1) and minimum (-1,-1), and anticlockwise in direction. (b) I know the solution is a quarter-wave plate oriented π/4, and half-wave plate at π/16, but don't understand how to reach there. I've obtained the polarisation vector (cos π/8, isin π/8) so far. I can't find much online guidance or textbook material working through this topic, so I'd appreciate any help I can get. Also, if anyone could let me know where I can get more...

Similar threads

Replies
4
Views
567
  • · Replies 8 ·
Replies
8
Views
2K
Replies
2
Views
2K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 6 ·
Replies
6
Views
3K
  • · Replies 7 ·
Replies
7
Views
3K
  • · Replies 2 ·
Replies
2
Views
2K
  • · Replies 20 ·
Replies
20
Views
4K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 6 ·
Replies
6
Views
5K