Finding the average height, z, of molecules in the box

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Homework Help Overview

The problem involves a box filled with classical ideal gas molecules under the influence of gravity, focusing on the distribution of molecular heights and the calculation of average height. The discussion centers around the mathematical formulation of the height distribution function and the implications of various limits.

Discussion Character

  • Exploratory, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • Participants discuss the normalization constant C and whether it is necessary to determine it for solving the problem. There are attempts to set up integrals for calculating the average height and to clarify the limits of the average height as the box height approaches zero and infinity.

Discussion Status

Some participants have made progress in setting up the integrals for the average height calculation, while others express confusion regarding the limits and the correctness of the expressions derived. There is an ongoing examination of the mathematical details and potential errors in signs or terms.

Contextual Notes

Participants note that the original problem may have been misinterpreted regarding the limits requested, suggesting that the average height should be denoted as z̄ instead of z. There is also a mention of missing information regarding the number of molecules, which affects the determination of the normalization constant.

SirCrayon
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Homework Statement


Let a box of height h be filled with classical ideal gas molecules of mass m in a constant gravitational filed g. As will be shown later, the distribution molecular height z obeys:

f(z) = C exp (-mgz/KT)

Where C is the normalization constant
a) find the average height z, of molecules in the box
b) find the limiting value of z when h->0
c) find the limiting value of z when h->infinitiy

The Attempt at a Solution



I am a little confused as to where to begin, should i start with determining C?

I started with:

Area * Height * average_density = number of molecules
= Area * integral (z = 0, H [constant*exp(-mgz/(kT))] dz
= Area*constant*(kT/(mg))*integral(0,mgH)/(kT) [exp(-u)]du
= Area*constant*(kT/(mg))*(1-exp(-mgH/(kT))

Therefore,
number = N = Area*constant*(kT/(mg))*(1-e^(-mgH/(kT))

So:
Constant = N*(mg/(kT))/(Area*(1-e^(-mgH/(kT))

Am i on the right track? thanks in advance
 
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It doesn't ask you to find C, so I think you can just use C as given and not bother with determining it. You can only find it by knowing N, which is not given.
 
Thanks,

I think i have figured out a) with the below:
<z> = ∫ z f(z) dz / ∫ f(z) dz

= ∫ z exp(-mgz/(kT)) dz / ∫ exp(-mgz/(kT)) dz

where the integrations are from z = 0 to z = h.

I am pretty stumped on b and c though
 
b) and c) as posted make no sense. It would make sense to ask for limiting values of the average height. Perhaps the original question has ##\bar z##?
 
Yes sorry, all the z's in a,b,c are z¯
 
Ok, so did you solve the integrals and get an answer for (a)?
 
Yes I have,

<z> = ∫ z f(z) dz / ∫ f(z) dz

= ∫ z exp(-mgz/(kT)) dz / ∫ exp(-mgz/(kT)) dz

= (kT)^2/(mg)^2 * (e^(-mgh/kT)*(-mgh/kT - 1) - 1)) / -(kT/mg)[(e-mg/h/KT)-1]
 
SirCrayon said:
(kT)^2/(mg)^2 * (e^(-mgh/kT)*(-mgh/kT - 1) - 1)) / -(kT/mg)[(e-mg/h/KT)-1]
In LaTex:
##\frac{\left(\frac{kT}{mg}\right)^2\left(e^{-\frac{mgh}{kT}}\left(-\frac{mgh}{kT} - 1\right) - 1\right) }{ -\frac{kT}{mg}\left(e^{-\frac{mgh}{kT}}-1\right)}##
Right? But I think you have a sign wrong - pls double check.
Some cancellation would be in order.
So b asks for the limit of the above as h tends to 0.
 
I can't seem to find the sign that's wrong, the only thing that I can reduce is the (KT/mg)^2 right? I can't figure out how to cancel anything else.

Setting h=0 should give me the term i need and same with inifinity for c). Thanks. But i can't seem to figure out the above
 
  • #10
I believe it should be ##\frac{\left(\frac{kT}{mg}\right)^2\left(e^{-\frac{mgh}{kT}}\left(-\frac{mgh}{kT} - 1\right) +1\right) }{ -\frac{kT}{mg}\left(e^{-\frac{mgh}{kT}}-1\right)}##, i.e. ##\frac{kT}{mg}\frac{1-e^{-\frac{mgh}{kT}}\left(1+\frac{mgh}{kT} \right) }{1 -e^{-\frac{mgh}{kT}}}##
What's an approximation for e-x for small x?
 

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