Free electron model (Sommerfeld model)

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SUMMARY

The discussion focuses on calculating the number of electron quantum states per unit volume in sodium using the free electron model, specifically within the energy interval of Fermi energy, ##\varepsilon_F = 3.22 eV##, and a small energy band width, ##\Delta \varepsilon = 0.02 eV##. The relevant equation is ##N=2V \cdot \frac{2 \pi}{h^3}(2m)^{\frac{3}{2}} E^{\frac{1}{2}} dE##, which allows for direct calculation without integration when ##\Delta \varepsilon## is sufficiently small. The solution approach emphasizes the importance of correctly interpreting the problem's requirements to find the number of states rather than total energy.

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steroidjunkie
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Homework Statement



Using free electron model find the number of electron quantum states per unit volume in ##[\varepsilon_F, \varepsilon_F + \Delta \varepsilon]## energy interval of sodium. Fermi energy of sodium is ##\varepsilon_F = 3.22 eV##, and energy band width is ##\Delta \varepsilon=0.02 eV##.

Homework Equations



##N=2V \cdot \frac{2 \pi}{h^3}(2m)^{\frac{3}{2}} E^{\frac{1}{2}} dE## - number of electrons in ##[\varepsilon_F, \varepsilon_F + \Delta \varepsilon]##
##E_{TOT}=\int_{\varepsilon_F}^{\varepsilon_F + \Delta \varepsilon} \frac{4 \pi V}{h^3}(2m)^{\frac{3}{2}} E^{\frac{1}{2}} E dE##

The Attempt at a Solution


[/B]
##E_{TOT}=\frac{4 \pi V 2m^{\frac{3}{2}}}{h^3} \cdot \frac{2}{5}( E_{F+\Delta \varepsilon}^{\frac{5}{2}} - E_{F}^{\frac{5}{2}})##
##E_{TOT}=
\frac{4 \pi V 2m^{\frac{3}{2}}}{h^3} \cdot \frac{2}{5}(3.24^{\frac{5}{2}} - 3.22^{\frac{5}{2}})##
##E_{TOT}=
\frac{4 \pi V 2m^{\frac{3}{2}}}{h^3} \cdot 0.12##

I don't know if this makes any sense so some input would be great.
 
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Note that the question asks for the number of electron states that have energies between ##\varepsilon_F## and ##\varepsilon_F + \Delta \varepsilon## for a unit volume of sodium assuming the free electron model. It does not ask for ##E_{TOT}## for this energy range.
steroidjunkie said:
##N=2V \cdot \frac{2 \pi}{h^3}(2m)^{\frac{3}{2}} E^{\frac{1}{2}} dE## - number of electrons in ##[\varepsilon_F, \varepsilon_F + \Delta \varepsilon]##
This equation will give you the answer directly if you consider ##\Delta \varepsilon## to be small enough that you can approximate ##dE## as ##\Delta \varepsilon##. No integration is needed.
 
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