Frequency of Electron Transition from (n+1) to n State

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Discussion Overview

The discussion revolves around the frequency of emitted radiation when an electron transitions from the (n+1) state to the nth state. Participants explore the relationship between the frequency and the principal quantum number n, particularly under the condition where n is much larger than 1 (n >> 1). The conversation includes attempts to solve a related equation and the implications of approximations in calculations.

Discussion Character

  • Homework-related
  • Mathematical reasoning
  • Exploratory

Main Points Raised

  • One participant presents an equation for frequency based on the transition states and seeks guidance on how to proceed with the calculations.
  • Another participant suggests checking the condition n >> 1 and proposes substituting a large value for n to simplify calculations.
  • Some participants discuss the implications of using approximations when n is large, noting that certain terms can be neglected.
  • There is a mention of the potential pitfalls of neglecting small quantities when subtracting nearly equal values, which could lead to incorrect conclusions.
  • One participant expresses confusion about the calculations and the use of a calculator during an exam setting, prompting discussions about alternative methods.
  • Several participants engage in back-and-forth clarifications regarding the correct approach to the problem and the reasoning behind their calculations.

Areas of Agreement / Disagreement

Participants exhibit a mix of agreement and disagreement regarding the methods of calculation and the implications of approximations. While some find the approximations helpful, others caution against neglecting terms that could affect the outcome.

Contextual Notes

Limitations in the discussion include the reliance on specific values for n and the assumptions made when applying the approximation n + 1 ≈ n. The discussion also highlights the challenge of handling small differences in calculations.

Saitama
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Homework Statement


When an electron makes a transition from (n+1) state to nth state, the frequency of emitted radiations is related to n according to (n>>1):
(a)[itex]v=\frac{2cRZ^2}{n^3}[/itex]
(b)[itex]v=\frac{cRZ^2}{n^4}[/itex]
(c)[itex]v=\frac{cRZ^2}{n^2}[/itex]
(a)[itex]v=\frac{2cRZ^2}{n^2}[/itex]

Homework Equations


[tex]\frac{1}{\lambda}=RZ^2(\frac{1}{n_1^2}-\frac{1}{n_2^2})[/tex]

The Attempt at a Solution


Solving the above equation and substituting the values i get:-
[tex]v=cRZ^2(\frac{1}{n^2}-\frac{1}{(n+1)^2})[/tex]

[tex]v=cRZ^2(\frac{2n+1}{n^2(n+1)^2})[/tex]

Now i am stuck, what should i do next?
 
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It's always a good idea when you're having trouble with a math problem to check whether you've used all the information given. You haven't used n>>1.
 
pmsrw3 said:
It's always a good idea when you're having trouble with a math problem to check whether you've used all the information given. You haven't used n>>1.

I don't know how should i use n>>1? :confused:
 
Well, try an example. Substitute in a big n, 100 for instance, and see what you get. Check whether it's closer to a, b, c, or d. Then try to figure out why.
 
pmsrw3 said:
Well, try an example. Substitute in a big n, 100 for instance, and see what you get. Check whether it's closer to a, b, c, or d. Then try to figure out why.

That's a lot of calculation if i substitute n=100, and i am not able to solve it.
When i substitute n=100, i get:-
[tex]v=cRZ^2(\frac{201}{10000(10201)})[/tex]
 
Pranav-Arora said:
if i substitute n=100, and i am not able to solve it.
When i substitute n=100, i get:-
[tex]v=cRZ^2(\frac{201}{10000(10201)})[/tex]
There's nothing to solve! Just punch it into your calculator and see what you get. Or use http://www.google.com/landing/searchtips/#calculator". Then do the same for the four choices you're given.

That's a lot of calculation
No, that is not a lot of calculation. That's a small amount of easy calculations. You need to get used to calculating things if you're going to be taking science classes.
 
Last edited by a moderator:
pmsrw3 said:
There's nothing to solve! Just punch it into your calculator and see what you get. Or use http://www.google.com/landing/searchtips/#calculator". Then do the same for the four choices you're given.

Sorry, i can't use a calculator, this question is from my exam paper and in the examination room we were not allowed to use a calculator, so any other way to solve it?
 
Last edited by a moderator:
Are you in the exam room now? If so, you shouldn't be asking for help. If not, then you can use a calculator.
 
pmsrw3 said:
Are you in the exam room now? If so, you shouldn't be asking for help. If not, then you can use a calculator.

No, don't talk silly, how can i be in the examination room and post a question?
 
  • #10
So use a calculator.
 
  • #11
Ok i did it using a calculator, i get my answer to be (a) option.
 
  • #12
Good. Now see if you can figure out why it comes out so close. If it's not obvious, try a few other n's.
 
  • #13
I like Serena said:
Hi Pranav-Arora! :smile:

If n >> 1, you can neglect small amounts in additions.
So for instance, n + 1 ≈ n
In the example where you calculated with n=100, you should e.g. replace 201 by 200.

Can you do that in your expression?

Hi! :smile:
If i solve it as you said, i again get (a) option.
 
  • #14
But what's the correct method?
 
  • #15
My apologies pmsrw3, it was not my intention to interfere, so I deleted my post. :blushing:
 
  • #16
Pranav-Arora said:
But what's the correct method?
That's it. If you try a bunch of calculations, it should become obvious that when n is big, n is practically the same as n+1, and 2n is practically the same as 2n+1.
 
  • #17
pmsrw3 said:
That's it. If you try a bunch of calculations, it should become obvious that when n is big, n is practically the same as n+1, and 2n is practically the same as 2n+1.

Thank you so much, i got it! :smile:
 
  • #18
Well, there is a catch...
What happens if you apply this estimation rule to your equation?

Pranav-Arora said:
Solving the above equation and substituting the values i get:-
[tex]v=cRZ^2(\frac{1}{n^2}-\frac{1}{(n+1)^2})[/tex]
 
  • #19
I like Serena said:
Well, there is a catch...
What happens if you apply this estimation rule to your equation?

It becomes zero.
 
  • #20
Any idea why?
And how you should handle it?
 
  • #21
I like Serena said:
Any idea why?
And how you should handle it?

No idea.
 
  • #22
Well, if you subtract 2 almost equal large quantities, the result is small but not zero.
This is something you can not neglect.
So (n+1) - n = 1 and this is not 0.

The trick is to eliminate subtractions, before you neglect stuff.
 
  • #23
I like Serena said:
Well, if you subtract 2 almost equal large quantities, the result is small but not zero.
This is something you can not neglect.
So (n+1) - n = 1 and this is not 0.

The trick is to eliminate subtractions, before you neglect stuff.

Thanks for clarification! :smile:
Can you please see to the thread "Atomic Structure Question" in "other Science".
tiny-tim replied that i should first find out the force, but i have never dealt with force in atomic structure. :confused:
 

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