Frequency of Photons in Hydrogen Gas: 100 Electrons in n=3 Orbit

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SUMMARY

The discussion centers on the behavior of 100 electrons in the n=3 orbit of hydrogen gas and their transitions to the ground state. The frequency of the photon required for an electron to transition from the ground state to the n=3 orbit is calculated as 2.9 x 1015 Hz. As the electrons return to their ground states, two distinct photon emission pathways are identified: 3 → 1 and 3 → 2 → 1, leading to multiple frequencies being emitted. The exact frequencies of the emitted photons depend on the energy differences between the respective orbits.

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  • Understanding of quantum mechanics and electron energy levels
  • Familiarity with hydrogen atom transitions and photon emission
  • Knowledge of frequency calculation using the formula E = hf
  • Basic grasp of spectroscopy and its applications
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  • Research the energy levels of hydrogen atoms and the associated photon frequencies
  • Learn about the Rydberg formula for calculating spectral lines
  • Explore the concept of transition probabilities in quantum mechanics
  • Study the differences between hydrogen atoms and hydrogen molecules (H2) in terms of energy levels
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Students and professionals in physics, particularly those studying atomic structure, quantum mechanics, and spectroscopy, will benefit from this discussion.

abohn1
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1. In a collection of hydrogen gas, 100 electrons are located in the n=3 orbit.

A. What is the frequency of a photon that could have been absorbed to cause an
electron to transition from its ground state to the n=3 orbit?

Now, as these electrons return to their ground states, assume that every available transition
is equally likely to happen (i.e. if there are two options, will take each option).

B. How many different frequencies will be seen in the photons emitted as the
electrons return to their ground state?

C. What are the frequencies?

D. How many photons of each frequency will be seen?

I think I'm okay on part A, I got 2.9 x 10^15 Hz...but the rest I have no idea where to begin. A little help just on what approach to take?
 
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First of all, I hate to be pedantic, but a "collection of hydrogen gas" implies H2 molecules, not Hydrogen atoms. The energy levels in the molecule are completely different. Unless you were given the energy of the levels in an H2[\SUB] molecules, it seems unlikely that you're asked to derive them, so I will assume that they are talking about a collection of Hydrogen atoms.

A. I get the same answer as you.

B. You have electrons in level 3. They will decay to level 1. There are two possible decay "routes": either 3 -> 1 or 3 -> 2 -> 1. Each jump results in the emission of a photon (at least that's what I assume from the question). You should be ok with the rest.
 

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