From Hot to Cool: A Change in Entropy

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SUMMARY

The net change in entropy (ΔSsys) of a system consisting of 1.0 kg of water at 20°C mixed with 1.0 g of ice at 0°C is calculated to be 0.084 J/K. The calculations involve determining the entropy change of the ice (ΔSice) using the heat of fusion (Lf = 3.34 x 10^5 J/kg) and the entropy change of the water (ΔSwater) based on the heat lost to the ice. The correct approach confirms that the temperature of the system remains constant during the melting process, leading to the final entropy value.

PREREQUISITES
  • Understanding of thermodynamics principles, specifically entropy.
  • Familiarity with heat transfer concepts, particularly heat of fusion.
  • Knowledge of basic calculus for entropy calculations.
  • Proficiency in using the formula S = Q/T for entropy change.
NEXT STEPS
  • Study the concept of entropy in thermodynamic systems.
  • Learn about the heat transfer mechanisms in phase changes.
  • Explore the implications of constant temperature processes in thermodynamics.
  • Review the calculations for heat transfer and entropy changes in calorimetry.
USEFUL FOR

This discussion is beneficial for students studying thermodynamics, particularly those focusing on entropy calculations in calorimetry, as well as educators seeking to clarify concepts related to heat transfer and phase changes.

kristibella
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Homework Statement


In a well-insulated calorimeter, 1.0 kg of water at 20o C is mixed with 1.0 g of ice at 0o C.

What is the net change in entropy Delta Ssys of the system from the time of mixing until the moment the ice completely melts? The heat of fusion of ice is Lf=3.34x105 J/kg.
Note that since the amount of ice is relatively small, the temperature of the water remains nearly constant throughout the process. Note also that the ice starts out at the melting point, and you are asked about the change in entropy by the time it just melts. In other words, you can assume that the temperature of the "ice water" remains constant as well.

Homework Equations


Ssys = Sice+Swater
Delta Sice = Qice/T
Qwater = -Qice (amount of heat lost to the ice)
Delta Swater = -Qice/T

The Attempt at a Solution


Delta Sice = (0.001 kg * 3.34x105 J/kg)/(0+273) = 1.22
Delta Swater = -334/(20+273) = -1.14
Delta S sys = 996.59

I think that this could be the correct answer, however, I would just like verification that it is correct. I have gotten the answer 1200, which seems to be a popular answer amongst my classmates, and it was not correct.
 
Last edited:
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I don't know about your numbers, but your approach looks good. Oh, it looks like you made a mistake inputting the value for Q_water.
 
Thank you for point it out! I found the correct answer of 0.084 J/K.
 
Last edited:

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