General electronic configuration of the d and f block elements

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SUMMARY

The general electronic configuration for d-block elements is defined as (n-1)d1-10ns0-2, as stated in the textbook referenced in the discussion. For f-block elements, the configuration is (n-2)f1-14ns2, with the addition of (n-1)d0-1 being applicable only in specific cases due to exceptions outlined in the Madelung rule. The presence of f-orbitals in periods 6 and 7 necessitates the inclusion of (n-2)f0-14 for a comprehensive understanding of these elements.

PREREQUISITES
  • Understanding of electron configurations in quantum chemistry
  • Familiarity with the Aufbau principle
  • Knowledge of the Madelung rule
  • Basic concepts of periodic table organization
NEXT STEPS
  • Study the Aufbau principle in detail
  • Research the Madelung rule and its exceptions
  • Explore the electronic configurations of lanthanides and actinides
  • Learn about the role of f-orbitals in chemical bonding
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Chemistry students, educators, and professionals interested in the electronic structure of transition metals and inner transition metals.

Kaushik
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Is it ##(n-1)d^{1->10}ns^2 \ or \ (n-1)d^{1->10}ns^{0->2}## ? My textbook says it is the latter. But I feel like it should be the former. Moreover, period 6 and 7 has the presence of f-orbitals. So adding## (n-2)f^{0->14}## would make it more general. Isn't it?

And also what about the f-block elements? Is it ##(n-2)f^{1->14}ns^2 \ or \ (n-2)f^{1->14}(n-1)d^{0->1}ns^2## ? I feel like it should be the former as the electrons are being added to (n-2) f before (n-1) d. I doubt the second one is correct unless there are any exceptions. But it is just my perception.
Please correct me if I am wrong :)
 
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