When people talk about the deflection of light being twice that of the Newtonian value due to spatial curvature, they are not talking about either the Einstein or the Riemann curvature tensors.
They are talking about something else, the Christoffel symbols.
If you write the equation for a body falling directly into a massive body in a Scwarzschild metric, you get a differential equation (the geodesic equation of motion) that looks like this.
[tex]\frac{d^2 r}{d \tau^2} + \Gamma^r{}_{tt} \left( \frac{dt}{d\tau} \right) ^2 + \Gamma^r{}_{rr} \left( \frac{dr}{d\tau} \right)^2 = 0[/tex]
(This is the simplest case, there are similar terms due to [itex]\Gamma^r{}_{\theta \theta}[/itex] and [itex]\Gamma^r{}_{\phi \phi}[/itex] in the more general expression.
If the velocity is much lower than 'c', [itex]dt/d\tau[/itex] is essentially one, and [itex]dr/d\tau[/itex] is << 1. In this case, the acceleration of an object is essentially constant and independent of its velocity.
We can therefore identify the Christoffel symbol [itex]\Gamma^r{}_{tt}[/itex] with radial gravitational acceleration in the Newtonian limit.
This is no longer the case when [itex]dr/d\tau[/itex] becomes of an order of magnitude near unity - the second term in the differential equation of motion becomes important.
The first Christoffel symbol involves only two time subscripts, the second Christoffel symbol involves only spatial subscripts. Because the name "Christoffel symbol" scares people, sometimes they are talked about as curvatures, though strictly speaking they are not. Note that the first symbol has only time-like subscripts, which is why it is sometimes very losely called a "time curvature", and the second symbol has only spatial subscripts.