Ground State Energy: What Regulates & Why is it Constant?

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Discussion Overview

The discussion revolves around the regulation of the ground state energy of a hydrogen atom, exploring why it remains constant. Participants delve into theoretical frameworks, forces involved, and the implications of quantum mechanics and electrostatics.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested
  • Conceptual clarification

Main Points Raised

  • Some participants reference perturbation theories and the Kohn-Sham equation as methods for calculating ground state energy.
  • There is a question about which force regulates the ground state energy and its relation to the Lorentz force.
  • One participant explains that the ground state energy arises from the solution of Schrödinger's equation for the Coulomb potential between the electron and proton.
  • Another participant questions the meaning of "regulate" in the context of ground state energy.
  • Participants discuss the binding force potential and kinetic energy values associated with the ground state, noting the Coulombic potential in the Rydberg atom model.
  • There are inquiries about why the electron energy remains constant in ground state hydrogen and the average size of the atom.
  • Some participants express confusion regarding the interaction between protons and anti-protons compared to protons and electrons, with references to baryons and leptons.
  • One participant speculates on the interaction of the ground state electrostatic potential with the zero-point field and its influence on ground state energy.
  • Discussions arise about the size of the electron in relation to the proton and the implications of this size on their interactions.
  • There are mentions of electron capture and the resulting neutron, along with references to beta decay.

Areas of Agreement / Disagreement

Participants express various viewpoints, with no consensus reached on the regulation of ground state energy, the size of the electron, or the interactions between different particles. The discussion remains unresolved with competing perspectives on these topics.

Contextual Notes

Participants reference various theoretical frameworks and concepts, but there are limitations in the clarity of definitions and assumptions regarding particle sizes and interactions. The discussion includes unresolved mathematical and conceptual steps.

nuby
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What regulates the ground state energy of a hydrogen atom? Why is it constant (more or less)?
 
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check perturbation theories ;)
 
hi,

as far as I know there are theoretical relations by which you calculate the ground state of a system. Like Kohn-Sham equation and ...
The density functional theory texts may help you. The atomic systems usually converge to a ground state energy which is unique, but theoretically very hard to calculate...

Hope it helped.

Good luck!
 
Thanks for the post. I was mostly wondering which force regulates the ground state, and if it is related to the Lorentz force.
 
The ground state energy of hydrogen comes from the solution of Schrödinger's equation for the Coulomb (electric) potential energy function of the electron and proton.
 
nuby said:
What regulates the ground state energy of a hydrogen atom? Why is it constant (more or less)?

What exactly do you mean by "regulate"?

Zz.
 
ZapperZ said:
What exactly do you mean by "regulate"?

Zz.

"Holds" the binding force (potential?) at around -27.2 eV , and electron kinetic energy at +13.6 eV.
 
nuby said:
"Holds" the binding force (potential) at around -27.2 eV , and electron kinetic energy at +13.6 eV.

Binding force potential? Kinetic energy?

Even in the simplest Rydberg atom model, is it not obvious that we have a Coulombic potential? I mean, you have a positive nucleus, and a negative electron. Is there something here that I'm missing?

Zz.
 
ZapperZ said:
Binding force potential? Kinetic energy?

Even in the simplest Rydberg atom model, is it not obvious that we have a Coulombic potential? I mean, you have a positive nucleus, and a negative electron. Is there something here that I'm missing?

Zz.
That works too, the Coulombic potential of ground state. What controls it?
 
  • #10
nuby said:
That works too, the Coulombic potential of ground state. How is it determined?

Er... this is classical E&M. If you have a spherically symmetry + charge at the origin, what is the electrostatic potential at point r?

Zz.
 
  • #11
I meant "what controls it" .. I edited my post right after you responded.
 
  • #12
nuby said:
I meant "what controls it" .. I edited my post right after you responded.

Control?

This is meant to clarify?

What's the issue that you have with electrostatic potential?

Zz.
 
  • #13
nuby said:
"Holds" the binding force (potential?) at around -27.2 eV , and electron kinetic energy at +13.6 eV.

I am guessing you mean that why does the electron not gain more then 13.6 ev of kinetic energy as it falls closer to the proton?

On the lower end, I don't think that the electron needs to keep at least 13.6 ev of kinetic energy, the electrons kinetic energy can be much lower and I think usually would be. Hydrogen gas with electrons buzzing around with 13.6 ev of energy would be considered very "hot".
 
  • #14
these might make more sense.

1.) Why does the electron energy remain constant in ground state hydrogen, as well as the average size of the atom?

2.) Why don't protons and anti-protons interact like protons and electrons?

Thanks in advance
 
  • #15
nuby said:
these might make more sense.

1.) Why does the electron energy remain constant in ground state hydrogen, as well as the average size of the atom?

Because when you set it up quantum mechanically, you get solutions to the Hamiltonian that corresponds to the "stationary" solutions that you get when you solve the classical Hamiltonian. Based on the physics that we know, this is the definition of the ground state.

2.) Why don't protons and anti-protons interact like protons and electrons?

Thanks in advance

Because a proton is a baryon and an electron is a lepton, where is a proton/anti-proton are both baryon and the physics indicates that they are "mirror image" of each other, separated only by a few symmetry operations. You can't do the same with proton and electrons, which are both matter and not even identical to each other in many respects.

Have you looked at basic physics text (or even the internet) to actually do your own legwork on the obvious difference between these two sets of conditions that you have asked? I mean, I'm sure you would have realized that proton-antiproton are more alike to each other than proton-electron. They do at least teach such a thing in high school, don't they, regarding the "scale" of things, such as the different in mass between proton and electron?

Zz.
 
  • #16
ZapperZ said:
Because a proton is a baryon and an electron is a lepton, where is a proton/anti-proton are both baryon and the physics indicates that they are "mirror image" of each other, separated only by a few symmetry operations. You can't do the same with proton and electrons, which are both matter and not even identical to each other in many respects.
Zz.

So the forces between the two leptons (electrons / positrons) behave a lot differently, than between leptons and baryons.
 
  • #17
You notice that you have changed topic.

I still want to know why you are having problems with a simple, straight-forward electrostatic potential.

Zz.
 
  • #18
I guess I'm wondering if the ground state electrostatic potential (or electron) interacts with the zero-point-field, and if the ZPF dictates the ground state energy?
 
  • #19
I doubt it.

the reason the electron can't fall into the proton is that it is too big. a proton and an antiproton are the same size so they can cancel each other out completely. a proton and an electron can't do that.

how big the electron is depends on how you define it. I prefer to think of the size of the electron as the size of its charge cloud.
 
  • #20
granpa said:
I doubt it.

the reason the electron can't fall into the proton is that it is too big. a proton and an antiproton are the same size so they can cancel each other out completely. a proton and an electron can't do that.
This seems strange. Are you saying a proton can't fall into an electron because they don't have the same mass-energy, or volume?
 
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  • #21
there is nothing in my post about a proton falling into a proton which would be strange indedd since they would electrostatically repel one another.

all I said was that the electron is (much) bigger than a proton.
 
  • #22
granpa said:
there is nothing in my post about a proton falling into a proton which would be strange indedd since they would electrostatically repel one another.

all I said was that the electron is (much) bigger than a proton.

I meant proton / electron. I'm still not clear on what your are saying. Are you saying the electron is so small it passes through the proton, which is why they don't 'crash' into each other?
 
  • #23
read post 21 again
 
  • #24
"the reason the electron can't fall into the proton is that it is too big." What is this supposed to mean?
 
  • #25
it means that it (the electron) is too big
 
  • #26
of course, the electron does fall into the proton during electron capture. the result is a neutron. but neutrons are unstable. they spontaneously break back down into protons and electrons (beta decay) with a considerably release of energy.

you might find this interesting.
http://physics.nist.gov/GenInt/Parity/expt.html
 
Last edited by a moderator:
  • #27
granpa said:
it means that it (the electron) is too big

Can you please go to the Particle Data Book and show me where an electron is "much bigger" than a proton?

Zz.
 
  • #28
can you please read post 19.
 
  • #29
granpa said:
can you please read post 19.

I did! That is why I asked you to look up in the Particle Data Book and (i) find out what is meant by the SIZE of an electron and (ii) why it is significantly larger than a proton.

According to your definition, if I throw a tennis ball around a tennis court, the SIZE of the tennis ball is as large as the tennis court itself. Does this make any sense to you? And more importantly, is this ACCURATE?

Zz.
 
  • #30
granpa said:
can you please read post 19.

granpa said:
how big the electron is depends on how you define it. I prefer to think of the size of the electron as the size of its charge cloud.

Proof by preference?

ZapperZ is exactly right with his tennis court analogy.
 
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