H20 Polar: Oxygen Electronegativity Causes Electron Disparity

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Discussion Overview

The discussion revolves around the polarity of water (H2O) and carbon dioxide (CO2), focusing on the role of electronegativity, molecular geometry, and the resulting dipole moments. Participants explore the differences in molecular structure and how these affect polarity, with references to concepts from chemistry.

Discussion Character

  • Exploratory
  • Debate/contested
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • Some participants assert that the higher electronegativity of oxygen compared to hydrogen causes electrons to be more localized around the oxygen atom.
  • Others question the role of molecular shape in determining polarity, specifically comparing the bent shape of water to the linear shape of carbon dioxide.
  • A participant notes that in CO2, the two polar bonds cancel each other out due to their linear arrangement, while in H2O, the bent shape prevents cancellation, resulting in a net dipole moment.
  • Some participants express confusion about the geometric shapes of the molecules and the forces that dictate these geometries.
  • There are suggestions for resources, including chemistry texts and websites, to help clarify these concepts.

Areas of Agreement / Disagreement

Participants generally agree on the influence of electronegativity and molecular shape on polarity, but there is ongoing debate regarding the specifics of how these factors interact, particularly in the context of CO2 and H2O. The discussion remains unresolved with multiple viewpoints presented.

Contextual Notes

Some participants express uncertainty regarding the underlying forces that determine molecular geometry and the implications for polarity. There are references to educational resources, indicating a range of familiarity with the topic among participants.

Who May Find This Useful

This discussion may be useful for students studying chemistry, particularly those interested in molecular polarity and the factors influencing molecular geometry.

LogicalAcid
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The electronegativity of Oxygen is higher than that of H, thus the electrons tend to stay a little more on the oxygens electron orbitals, right?
 
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That's true, but that's not all true. Think about molecule shape.
 
Just to expand on what Borek has said.

Why is carbon dioxide not polar while water is polar (in terms of net dipole not polarity of individual bonds)?
 
Yanick said:
Just to expand on what Borek has said.

Why is carbon dioxide not polar while water is polar (in terms of net dipole not polarity of individual bonds)?

Hmmm, I do not know. Because if oxygen has a much higher electronegativity than C, I don't know why.
 
Remember that these are charges, and if we have two equal charges acting in opposite directions, they will cancel each other out.
 
Why is H20 polar, and C02 not?

I mean, if oxygen has a higher electronegativity than Hydrogen, I can see why H20 is a polar bonds, the electrons orbit around O a little more than the two H atoms. But why isn't C02 polar?
 


CO2 is a linear molecule; the two polar bonds point in opposite directions, and cancel each other out.

Since H20 is a bent molecule, the two polar bonds don't cancel each other.

EDIT:
Here's an image of a water molecule: the left side is more negative than the right side, resulting in an overall dipole moment for the molecule:

[URL]http://bioweb.wku.edu/courses/biol115/Wyatt/water1.gif[/URL]
 
Last edited by a moderator:


Redbelly98 said:
CO2 is a linear molecule; the two polar bonds point in opposite directions, and cancel each other out.

Since H20 is a bent molecule, the two polar bonds don't cancel each other.

EDIT:
Here's an image of a water molecule: the left side is more negative than the right side, resulting in an overall dipole moment for the molecule:

[URL]http://bioweb.wku.edu/courses/biol115/Wyatt/water1.gif
[/URL]

I see, just how like charges in a regular atom cancel each other out? Thank you for the answer.
 
Last edited by a moderator:
I see, thank you
 
  • #10
LogicalAcid said:
I see, thank you

Just in case you only think you see - what is geometry of both molecules? CO2? H2O?
 
  • #11
Borek said:
Just in case you only think you see - what is geometry of both molecules? CO2? H2O?

Well that is what I don't understand, if they are both covalent, what forces cause them to bond with the geometry they have e.g linear or bent bonds?
 
  • #12
Do you own a General Chemistry text? I would suggest purchasing one, these are things that are pretty clearly explained in the text that I own.

As far as your current question:
http://www.chem.purdue.edu/gchelp/vsepr/
 
  • #13
Yanick said:
Do you own a General Chemistry text? I would suggest purchasing one, these are things that are pretty clearly explained in the text that I own.

As far as your current question:
http://www.chem.purdue.edu/gchelp/vsepr/

My middle school doesn't have a library, and the library near me have few but I will check.
 
  • #14
Wait, you go to middle school and you're trying to learn college level general chemistry?
 
  • #16
Yanick said:
Wait, you go to middle school and you're trying to learn college level general chemistry?

Studying physics to, along with astrochemistry.
 
  • #17
:eek:
 

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