Henry's law applied to a solution of a solute in a solvent

  • Context: Chemistry 
  • Thread starter Thread starter havenly
  • Start date Start date
  • Tags Tags
    Applied Law Solvent
Click For Summary
SUMMARY

The discussion centers on the application of Henry's law to solutions, specifically evaluating the correctness of various options regarding the law's implications. Participants agree that option A is correct, while option B is definitively incorrect due to the misinterpretation of the relationship k = pB*. Options C and E are debated, with some asserting their correctness based on the definitions of Henry's constant and ideal dilute solutions. The conversation highlights the nuances of interpreting Henry's law alongside Raoult's law in ideal solutions.

PREREQUISITES
  • Understanding of Henry's law and its application to solutions
  • Familiarity with Raoult's law and its relationship to ideal solutions
  • Knowledge of the dimensions of physical constants in chemistry
  • Ability to interpret graphical representations of pressure and concentration
NEXT STEPS
  • Research the different forms of Henry's law and their applications
  • Study the relationship between partial pressure and mole fraction in ideal solutions
  • Examine the implications of Raoult's law in the context of non-ideal solutions
  • Explore case studies that illustrate the practical applications of Henry's law in various solute-solvent systems
USEFUL FOR

Chemistry students, researchers in physical chemistry, and professionals involved in solution chemistry and thermodynamics will benefit from this discussion.

havenly
Messages
9
Reaction score
0
Homework Statement
Let a solution of a solute B in a solvent A the vapour pressure is represented on the cluster below

A.The region in circle 1 accounts for the behavior of the solute in an ideally diluted solution
B.The vapour pressure of B is equal to Henry's constant in the case of an ideal solution?
C.Henry's constant is dimensional
D.Vapour pressure PB* corresponds to atmospheric pressure
E.The region in circle 2 accounts for the behaviour of the solvent in an ideally diluted solution.

I think it's B That's right?
Relevant Equations
;
1.jpg
 
Last edited by a moderator:
Physics news on Phys.org
I do not agree. Explain why you think so ...

Also: please explain why you think A, C, D, E are not correct...

##\ ##
 
i think
option b is incorrect because k= pB* i.e. the pressure of the pure body in an ideal solution
C. henry's constant has the dimensions of a pressure
D.la steam pressure of pB* corresponds to the pression of the pure body.
E. a solution ideally diluted follows Henry's law and in circle 2 we see raoult's law.
the correct answer is a?
 
havenly said:
option b is incorrect because k= pB* i.e. the pressure of the pure body in an ideal solution
I find your picture difficult to read, but it seems to me the top right symbol is ##K_B## and the straight line says 'Ideal dilute solution (Henry's law)'.

In region 1 the ##p(x_B)## follows the straight line closely, so there you have ##p = K_B \,x_B##.
(so not k= pB* !)
In this case the constant ##K_B## has the dimension of pressure / mole fraction, i.e. it is not dimensionless.
(so doesn't that mean that answer C is correct too ? Unfortunately there are several forms of Henry's law -- also check here)

I can only assume that the ordinate is the partial pressure of B, although the axis title is 'Pressure'.

In summary: A seems correct, B definitely not, C seems correct too. D is nonsense and E can be argued correct as well: in that region component B can be considered to be 'the solvent'

I request a second opinion from @Chestermiller

##\ ##
 
I don’t think that E is correct.
 
  • Like
Likes   Reactions: BvU
please you can explain to me why e is correct and not the a @Chestermiller
 
havenly said:
please you can explain to me why e is correct and not the a @Chestermiller
I agree with @BvU. It seems to me that both A and C are correct.
 
  • Like
Likes   Reactions: chemisttree

Similar threads

  • · Replies 3 ·
Replies
3
Views
2K
  • · Replies 5 ·
Replies
5
Views
2K
  • · Replies 6 ·
Replies
6
Views
3K
  • · Replies 3 ·
Replies
3
Views
2K
Replies
2
Views
3K
  • · Replies 7 ·
Replies
7
Views
2K
  • · Replies 4 ·
Replies
4
Views
4K
  • · Replies 36 ·
2
Replies
36
Views
8K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 2 ·
Replies
2
Views
2K