Henry's law applied to a solution of a solute in a solvent

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Discussion Overview

The discussion revolves around the application of Henry's law to a solution of a solute in a solvent, with participants evaluating various statements related to the law and its implications in ideal solutions. The scope includes theoretical considerations and interpretations of Henry's law and Raoult's law.

Discussion Character

  • Debate/contested
  • Technical explanation

Main Points Raised

  • Some participants argue that option B is incorrect because it misrepresents the relationship between Henry's constant and the pressure of the pure substance.
  • There is a claim that Henry's constant has dimensions of pressure, which challenges the correctness of option C.
  • One participant suggests that the steam pressure of the pure substance corresponds to the pressure of the pure body, questioning the validity of option D.
  • Participants discuss the interpretation of a graphical representation, indicating that in a certain region, the behavior of the solution aligns with Henry's law.
  • Some participants propose that both options A and C could be correct based on their interpretations of the law.
  • There is a request for clarification regarding the correctness of option E, with some participants expressing disagreement with its validity.

Areas of Agreement / Disagreement

Participants express multiple competing views regarding the correctness of options A, B, C, D, and E, indicating that the discussion remains unresolved with no consensus reached.

Contextual Notes

Participants note the complexity of Henry's law, including various forms and interpretations, which may affect the understanding of the statements being evaluated.

havenly
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Homework Statement
Let a solution of a solute B in a solvent A the vapour pressure is represented on the cluster below

A.The region in circle 1 accounts for the behavior of the solute in an ideally diluted solution
B.The vapour pressure of B is equal to Henry's constant in the case of an ideal solution?
C.Henry's constant is dimensional
D.Vapour pressure PB* corresponds to atmospheric pressure
E.The region in circle 2 accounts for the behaviour of the solvent in an ideally diluted solution.

I think it's B That's right?
Relevant Equations
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1.jpg
 
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I do not agree. Explain why you think so ...

Also: please explain why you think A, C, D, E are not correct...

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i think
option b is incorrect because k= pB* i.e. the pressure of the pure body in an ideal solution
C. henry's constant has the dimensions of a pressure
D.la steam pressure of pB* corresponds to the pression of the pure body.
E. a solution ideally diluted follows Henry's law and in circle 2 we see raoult's law.
the correct answer is a?
 
havenly said:
option b is incorrect because k= pB* i.e. the pressure of the pure body in an ideal solution
I find your picture difficult to read, but it seems to me the top right symbol is ##K_B## and the straight line says 'Ideal dilute solution (Henry's law)'.

In region 1 the ##p(x_B)## follows the straight line closely, so there you have ##p = K_B \,x_B##.
(so not k= pB* !)
In this case the constant ##K_B## has the dimension of pressure / mole fraction, i.e. it is not dimensionless.
(so doesn't that mean that answer C is correct too ? Unfortunately there are several forms of Henry's law -- also check here)

I can only assume that the ordinate is the partial pressure of B, although the axis title is 'Pressure'.

In summary: A seems correct, B definitely not, C seems correct too. D is nonsense and E can be argued correct as well: in that region component B can be considered to be 'the solvent'

I request a second opinion from @Chestermiller

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I don’t think that E is correct.
 
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please you can explain to me why e is correct and not the a @Chestermiller
 
havenly said:
please you can explain to me why e is correct and not the a @Chestermiller
I agree with @BvU. It seems to me that both A and C are correct.
 
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