Highery energy photon on lower band gap semiconductor

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Discussion Overview

The discussion centers around the ability of semiconductors to absorb photons with energies greater than their band gap energy (Eg), specifically in the context of infrared detectors like InAs. Participants explore the implications of such absorption on the detection of different electromagnetic (EM) waves and the transparency of semiconductors to visible light.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant questions whether a semiconductor can absorb a photon with energy greater than its band gap and transition an electron from the valence band to the conduction band, using InAs as an example.
  • Another participant confirms that a semiconductor can indeed absorb higher energy photons, noting that the electron may initially be excited above the conduction band edge before thermalizing back down.
  • A later reply introduces the concept of photoemission, suggesting that excited electrons can escape to the vacuum level, which may be relevant for certain applications.
  • Some participants express uncertainty about the absorption efficiency of semiconductors, suggesting it may depend on the wavelength of the light relative to the band gap.

Areas of Agreement / Disagreement

Participants generally agree that semiconductors can absorb higher energy photons, but there is uncertainty regarding the specifics of absorption efficiency and the implications for detecting only infrared light versus other EM waves.

Contextual Notes

Participants mention that the absorption efficiency may be larger when the wavelength of light is close to the band gap of the semiconductor, indicating a potential limitation in understanding the full behavior of the materials involved.

itsbiprangshu
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Can a semiconductor absorb a higher energy photon than its Band gap Eg and make a transition from valence band to conduction band? For a example commonly used IR detector is InAs (semiconductor) whose Eg is 0.354 eV, if a blue light falls on it, will it able to absorve that energy and make a transition from valence band conduction band? If it is able to do that then how will we be sure that it is detecting only IR not any other EM waves? And if will not absorve higher energies will it be transparent to visible portion of light?
 
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What you're really asking goes deep into the device physics of a photodetector. For example, the image sensors on most cell phone are made of silicon but clearly they're designed to recognize the entire visible spectrum. I'll just deal with the basics for now...

To answer your question, yes, if you hit a semiconductor with with a photon of energy greater than that of the semiconductor, it will pump an electron to the conduction band. It's important to note that the electron will initially be pumped above the conduction band edge due to the extra energy. Usually the electron will then thermalize back down to the conduction band edge.

I initially meant the above description for a direct band semiconductor, but it easily generalizes to the indirect case.
 
cmos said:
What you're really asking goes deep into the device physics of a photodetector. For example, the image sensors on most cell phone are made of silicon but clearly they're designed to recognize the entire visible spectrum. I'll just deal with the basics for now...

To answer your question, yes, if you hit a semiconductor with with a photon of energy greater than that of the semiconductor, it will pump an electron to the conduction band. It's important to note that the electron will initially be pumped above the conduction band edge due to the extra energy. Usually the electron will then thermalize back down to the conduction band edge.

I initially meant the above description for a direct band semiconductor, but it easily generalizes to the indirect case.

Actually, this is not necessarily the only case. One can get photoemission from semiconductors as well, whereby the excited electrons escape to the vacuum level and leave the bulk material. In fact, in general, photocathodes with the highest quantum efficiency (certainly higher than metals) are semiconductors.

Zz.
 
I also have that kind of question.
I think it really does. But absorption efficiency may be depend on the light. The absorption efficiency is larger when the wavelength of the light is close to the bad gap of the semiconductor.
 
shreason said:
I also have that kind of question.
I think it really does. But absorption efficiency may be depend on the light. The absorption efficiency is larger when the wavelength of the light is close to the bad gap of the semiconductor.

Why?

Zz.
 

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