Why is the band offset of an LED equal to the band gap?

In summary, the conversation discusses using the threshold voltage of LEDs to determine Planck's constant through the relation of energy offset and band gap. The participants also question the validity of this experiment and seek further understanding.
  • #1
whonut
6
0
I am doing an experiment where we have to use the threshold voltage of LEDs to determine Planck's constant given the following relation

$$ eV_0 = E_g = \frac{hc}{\lambda} $$

where ## V_0 ## is the threshold voltage, ## \lambda ## is the wavelength of emitted light and ## E_g ## is the band gap.

After reading up, it is my understanding that ## eV_0 ## is the energy offset between the conduction band in the p-type and n-type regions of the p-n junction, which is caused by the electric field set up in the depletion layer. The right hand side is obviously the energy of the photon emitted by the LED when an electron transitions from the conduction to the valence band on one side of the junction. These two regions are separated by the band gap.

I am really struggling to see how the energy offset and the band gap can be equal like this. Any help would be much appreciated. Thank you.
 
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  • #2
You are right, this is a dubious experiment. It is impossible to understand the results from physics alone. If you look at the diode equation, there is no threshold voltage.
 

1. Why is the band offset of an LED important?

The band offset of an LED is important because it determines the energy levels and thus the efficiency of the device. It also affects the type of materials that can be used in the construction of the LED.

2. What is the relationship between the band offset and the band gap?

The band offset of an LED is equal to the difference in energy between the conduction band minimum (CBM) and the valence band maximum (VBM) of the two materials that make up the LED. This difference is also known as the band gap.

3. How does the band offset affect the performance of an LED?

The band offset directly affects the efficiency of an LED. A larger band offset leads to a more efficient LED as it allows for better electron and hole confinement and reduces the chances of recombination. On the other hand, a smaller band offset can result in lower efficiency and reduced light output.

4. Can the band offset of an LED be controlled?

Yes, the band offset of an LED can be controlled by changing the materials used in its construction. By selecting materials with different band gap energies, the band offset can be adjusted to meet the desired performance requirements.

5. How is the band offset of an LED determined?

The band offset of an LED can be determined experimentally by measuring the energy levels of the CBM and VBM of the two materials used in its construction. It can also be calculated using theoretical models and equations based on the band structure of the materials.

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