How can I determine the optimum cu-zn ratio for maximum hardness in brass?

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Discussion Overview

The discussion revolves around determining the optimum copper-zinc (Cu-Zn) ratio for achieving maximum hardness in brass, specifically focusing on the practical aspects of melting and mixing the metals for a science project. Participants explore various factors such as temperature, vaporization, and research strategies related to materials science.

Discussion Character

  • Exploratory
  • Technical explanation
  • Homework-related
  • Debate/contested

Main Points Raised

  • One participant seeks guidance on the melting temperature, timing for adding zinc, and the percentage of zinc lost due to vaporization during the brass-making process.
  • Another participant suggests that the melting temperature should balance sufficient heat for mixing and minimizing zinc vaporization, noting that the melting point of copper is a critical factor.
  • It is mentioned that the loss of zinc due to vaporization is influenced by multiple variables including time, pressure, and temperature, and that the vapor pressure of zinc at the melting temperature should be considered.
  • A participant expresses uncertainty about the optimum Cu-Zn ratio for maximum hardness, indicating that this is a materials science question related to the crystal structure formed during mixing.
  • There is a suggestion that increasing copper content may lead to increased hardness, as copper is harder than zinc.
  • Participants discuss the challenges of finding specific research information online, with one suggesting that forums may be a useful resource for such inquiries.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the optimum Cu-Zn ratio for maximum hardness, and multiple views regarding the factors affecting hardness and the brass-making process remain. Uncertainty exists about the specific composition ranges for alpha-beta brass.

Contextual Notes

Limitations include the lack of specific data on the relationship between Cu-Zn ratios and hardness, as well as the dependence on various experimental conditions that may affect outcomes.

abolger89
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I need some help with information for making brass for a science project. I have access to a furnace and professional help. I need to know at what temperature i should heat the furnace to, how long i should wait before adding the zinc, what % zinc is lost due to vaporization, and how long i should keep the brass in the furnace after adding the zinc. The zinc content will be 35%-45%.
 
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Who is your professional help... can they answer these questions?

Temperature: I think this would be a tradeoff between maintaining a sufficient temperature but minimizing vaporization. You will have more vaporization at a higher temperature, but you will probably also see better mixing or the copper and zinc. Theoretically, the minimum temperature necessary to achieve a molten state should be no higher than the standard melting point of copper (freezing point depression caused by adding zinc).

I don't know how long to wait. I don't see any benefit in waiting past the "full melt" point.

The % lost due to vaporization will depend on time, pressure, temperature, composition, etc. You could assume that at the interface of your liquid metals and atmosphere, the concentration of zinc vapor is equal to its vapor pressure at the temperature. Then you need to know how much the atmosphere is moving to determine the mass transport of zinc vapor.
 
A local institution is allowing me to to use their small furnace. They are only helping me actually carry out the procedure(for safety reasons).

Thanks this helped a lot.
 
abolger89 said:
A local institution is allowing me to to use their small furnace. They are only helping me actually carry out the procedure(for safety reasons).

Thanks this helped a lot.

What's your background?

I'd be happy to try and explain things more.

Also please update with whatever happens! I'm curious how this sort of thing works in practice.
 
I am a senior in high school. The project I'm working on is my extended essay for the IB program . I am currently taking my third year of chemistry and first year of physics. I'm trying to find the optimum ratio of cu-zn in alpha-beta brass for maximum hardness. I'm having a hard time researching, my questions seem to be too specific for the internet. Do you have any ideas on how to research this stuff? I appreciate your help.
 
abolger89 said:
I am a senior in high school. The project I'm working on is my extended essay for the IB program . I am currently taking my third year of chemistry and first year of physics. I'm trying to find the optimum ratio of cu-zn in alpha-beta brass for maximum hardness. I'm having a hard time researching, my questions seem to be too specific for the internet. Do you have any ideas on how to research this stuff? I appreciate your help.

Maximum hardness isn't something I've learned about. That would be a materials science question, and it would have to do with the crystal structure (or lack of it) that forms when the metals are mixed. I don't know how composition would affect it.

You mentioned alpha-beta brass. Is that a specified alloy, or does it have a specified composition range? I'd guess that as you increase the amount of copper, the hardness of the brass increases (copper is harder than zinc).

For researching, I think forums are the best. Also independent searching, of course, but some stuff is just too confusing.

This link explains some, especially at the bottom:
http://courses.chem.psu.edu/chem112/materials/metals.html
 

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