How can the enthalpy change of a NaNO3 solution be calculated using calorimetry?

  • Thread starter Thread starter jxs919
  • Start date Start date
  • Tags Tags
    Calorimetry
Click For Summary
To calculate the enthalpy change (ΔH) for dissolving 15.3g of NaNO3 in 100g of water, the heat (q) can be determined using the formula q = mCT, where m is the mass of water, C is the specific heat of water, and T is the temperature change. The final mass for calculations should include both the water and the dissolved NaNO3. While the specific heat of the solution can be approximated as that of water, a more accurate value can be found in chemistry handbooks. Incorporating these factors will yield ΔH in kJ for the dissolution process.
jxs919
Messages
8
Reaction score
0
lemme start off with the problem:

15.3g of NaNO3 were disssolved in 100 g of water in a calorimeter. The temperature of the water dropped from 25 C to 21.56 C. Calculate delta H for the solution process


here's what i figure:

delta H = q

q = MCT

M = mass of water

C = specific heat of water

T = change in temp


so plug and chug should get me my answer ?

i don't know why but i think i need to incorporate the mass of my NaNO3 somewhere...

help me please
 
Physics news on Phys.org
1. This question belongs in the homework & coursework subforum.

2. \Delta H = \Delta (mCT) = m_fC_fT_f - m_i C_iT_i
where f:final, i:initial
 
uhm thanks for the formula but I'm still lost

is the massfinal.. water + substance ?

and the C final.. how do i calculate that ? i only know the specific heat of water by itself
 
jxs919 said:
uhm thanks for the formula but I'm still lost

is the massfinal.. water + substance ?
Correct.

and the C final.. how do i calculate that ? i only know the specific heat of water by itself
I guess a reasonable approximation might be to use C(final) = C(initial) = C(water).

If you want to be more accurate, you can look up specific heats of solutions in a chemistry handbook like Lange or CRC (my guess is that you don't have to).
 
The experimental solution to this problem would need to incorporate the specific heat capacity of the calorimeter. Yes, you need to incorporate the mass of NaNO3 and the water to find the enthalpy in terms of, let's say, kJ/"____" for the dissolution process.
 

Similar threads

  • · Replies 9 ·
Replies
9
Views
2K
  • · Replies 3 ·
Replies
3
Views
3K
  • · Replies 16 ·
Replies
16
Views
3K
  • · Replies 12 ·
Replies
12
Views
3K
  • · Replies 1 ·
Replies
1
Views
4K
Replies
3
Views
2K
  • · Replies 2 ·
Replies
2
Views
3K
  • · Replies 19 ·
Replies
19
Views
4K
  • · Replies 1 ·
Replies
1
Views
3K
  • · Replies 4 ·
Replies
4
Views
3K