How can the enthalpy change of a NaNO3 solution be calculated using calorimetry?

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Discussion Overview

The discussion revolves around calculating the enthalpy change (ΔH) for the dissolution of sodium nitrate (NaNO3) in water using calorimetry. Participants explore the necessary formulas and considerations for accurately determining ΔH, including the roles of mass, temperature change, and specific heat capacities.

Discussion Character

  • Homework-related
  • Technical explanation
  • Conceptual clarification

Main Points Raised

  • One participant presents a problem involving the dissolution of 15.3g of NaNO3 in 100g of water, noting a temperature drop and seeking to calculate ΔH.
  • Another participant suggests using the formula ΔH = Δ(mCT) and provides a breakdown of the variables involved.
  • There is confusion regarding whether the final mass should include both the water and the dissolved substance, which is confirmed by a later reply.
  • Participants discuss the specific heat capacity, with one suggesting that it may be reasonable to approximate the final specific heat as that of water, while another mentions the potential need to consider the calorimeter's specific heat capacity for a more accurate calculation.

Areas of Agreement / Disagreement

Participants generally agree on the need to incorporate both the mass of NaNO3 and water into the calculations, but there is uncertainty regarding the specific heat capacity of the solution and whether additional resources are necessary for accuracy. The discussion remains unresolved regarding the best approach to account for these factors.

Contextual Notes

Limitations include the assumption that the specific heat of the solution can be approximated by that of water, and the potential oversight of the calorimeter's specific heat capacity in the calculations.

jxs919
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lemme start off with the problem:

15.3g of NaNO3 were disssolved in 100 g of water in a calorimeter. The temperature of the water dropped from 25 C to 21.56 C. Calculate delta H for the solution process


here's what i figure:

delta H = q

q = MCT

M = mass of water

C = specific heat of water

T = change in temp


so plug and chug should get me my answer ?

i don't know why but i think i need to incorporate the mass of my NaNO3 somewhere...

help me please
 
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1. This question belongs in the homework & coursework subforum.

2. \Delta H = \Delta (mCT) = m_fC_fT_f - m_i C_iT_i
where f:final, i:initial
 
uhm thanks for the formula but I'm still lost

is the massfinal.. water + substance ?

and the C final.. how do i calculate that ? i only know the specific heat of water by itself
 
jxs919 said:
uhm thanks for the formula but I'm still lost

is the massfinal.. water + substance ?
Correct.

and the C final.. how do i calculate that ? i only know the specific heat of water by itself
I guess a reasonable approximation might be to use C(final) = C(initial) = C(water).

If you want to be more accurate, you can look up specific heats of solutions in a chemistry handbook like Lange or CRC (my guess is that you don't have to).
 
The experimental solution to this problem would need to incorporate the specific heat capacity of the calorimeter. Yes, you need to incorporate the mass of NaNO3 and the water to find the enthalpy in terms of, let's say, kJ/"____" for the dissolution process.
 

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