How do molecules radiate photons and contribute to thermal radiation?

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Discussion Overview

The discussion centers on how molecules radiate photons and contribute to thermal radiation, particularly in the context of energy gain and the mechanisms behind photon emission. It explores theoretical concepts related to molecular behavior, thermal radiation, and the sources of emitted photons.

Discussion Character

  • Exploratory, Technical explanation, Conceptual clarification, Debate/contested

Main Points Raised

  • One participant questions how molecules radiate photons if heat loss through other means is considered zero, suggesting a need for clarification on the mechanism of photon emission.
  • Another participant emphasizes that if radiation is zero, then molecules would not radiate photons, indicating a potential misunderstanding of the initial premise.
  • It is noted that all molecules above absolute zero emit thermal radiation, which consists of photons, prompting inquiries about the source of these photons, such as whether they originate from electrons or nuclei.
  • A participant mentions that individual molecules do not possess a temperature, but rather that the temperature of a material relates to the average kinetic energy of its molecules.
  • Another contribution explains that the electromagnetic fields within heated materials, generated by the movement of charged particles, are responsible for the electromagnetic radiation emitted as photons.
  • Clarification is provided that the source of photons is the heated material itself, suggesting it may not be necessary to pinpoint a more specific origin.

Areas of Agreement / Disagreement

Participants express differing views on the implications of radiation being zero and the nature of photon emission, indicating that multiple competing perspectives remain without a consensus on the mechanisms involved.

Contextual Notes

There are unresolved questions regarding the definitions of temperature at the molecular level and the specific processes that lead to photon emission, which may depend on various assumptions about molecular behavior and energy states.

Zaya Bell
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If a substance gains energy, it's molecules vibrate faster and thus the material increases temperature. My question is if heat lost through any other means but radiation is zero, how exactly does these molecules radiate photons?
 
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Zaya Bell said:
if heat lost through any other means but radiation is zero
If radation is zero, the molecules do not radiate photons, so the question
Zaya Bell said:
how exactly do these molecules radiate photons?
appears a bit strange. Can you elucidate ?
 
BvU said:
If radation is zero, the molecules do not radiate photons, so the question
I'm saying that all other forms except radiation is zero.

BvU said:
appears a bit strange. Can you elucidate ?
It is said that all molecules above absolute zero emit thermal radiation which are actually photons. The question is, what is the source of the this photons? From the electron? nucleus? Where? And how?
 
Google for black body and from there for black body radiation, Rayleigh-Jeans, Wien, Planck etc.
Zaya Bell said:
I'm saying that all other forms except radiation is zero.
Ah, I misread, sorry.
Zaya Bell said:
It is said that all molecules above absolute zero emit thermal radiation which are actually photons.
correct -- up to a point: individual molecules do not have a temperature. They have velocities and thereby kinetic energy. The temperature of a macroscopic quantity of material has a temperature that is directly related to the average kinetic energy.
The question is, what is the source of the this photons? From the electron? nucleus? Where? And how?
any phenomenon that can absorb energy (e.g. molecular vibrations, rotations, electron orbits) to go into a state of higher energy can emit energy and end up in a lower energy state.

[edited the 'correct'a little...
 
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Zaya Bell said:
The question is, what is the source of the this photons? From the electron? nucleus? Where? And how?
The electromagnetic fields within the material are constantly changing because they are produced by the random movement of trillions of trillions of charged particles in the heated material. These changing fields are what causes the electromagnetic radiation.

So the source of the photons is the heated material, and it doesn't make sense to try to narrow it down further.
 
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BvU said:
individual molecules do not have a temperature.
Yeah, sorry. Wanted to say all molecules in a material above absolute zero.
 
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