How Do Reactor Types and Sizes Vary for Different Chemical Reactions?

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SUMMARY

The discussion focuses on the calculation of reactor volumes and times for a chemical reaction converting A to R, using data from Levenspiel's 1999 textbook. A batch reactor requires 10.21 minutes for the conversion, while a plug flow reactor (PFR) needs 130.8 L and a continuous stirred-tank reactor (CSTR) requires 25.6 L for the same conversion. The forum participants also explore the volumes of two flow reactors in series, with specific calculations yielding 38.7 L and 17.9 L for the first case, and 77.0 L and 85.4 L for the second case. The discussion emphasizes the importance of accurate data and integration methods for reactor design.

PREREQUISITES
  • Understanding of chemical reaction kinetics
  • Familiarity with reactor types: Batch, PFR, and CSTR
  • Knowledge of stoichiometry and concentration calculations
  • Proficiency in numerical integration techniques
NEXT STEPS
  • Study the integration methods for calculating areas under curves in reaction kinetics
  • Learn about the design and operation of Continuous Stirred-Tank Reactors (CSTR)
  • Explore the differences in performance between Plug Flow Reactors (PFR) and CSTR
  • Review Levenspiel's "Chemical Reaction Engineering" for detailed examples and methodologies
USEFUL FOR

Chemical engineers, process design engineers, and students studying chemical reaction engineering will benefit from this discussion, particularly those focused on reactor design and optimization.

atsum
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PER - chemical reaction

Q: A reactor is needed to convert A to R in a liquid reaction. The stoichiomentry is simply A→R and the rate data is given in the table below (P5.21, Levenspiel 1999).

h4l1G.jpg


For the reactant concentration to drop from CA0 = 1.3 mol/L to CAf =0.3 mol/L, determine,

a) the time required with a batch reactor. (ans: 10.21 min).

b) the volume required for a flow reactor to achieve the same conversion as in (a) and at
a feeding rate of A 1000 mol/h in (1) a PFR, and (2) a CSTR. (ans: PFR V= 130.8 L;
CSTR V = 25.6 L).

c) the volumes of two flow reactors in series with the exit concentration of A from the 1st
reactor xA1= 0.231 (i.e. CA1= 1 mol/L) for (1) 1st PFR +2nd CSTR, and (2) 1st CSTR
+2nd PFR. For both cases, sketch the area for each reactor in the 1/rA-xA plot. (ans: 1,
V1= 38.7 L,V2 17.9 L; 2, V1= 77.0 L, V2 = 85.4 L).

Hints: Plot 1/rA vs. xA, calculate the area under the line, either by measuring the graphical
area or by integration of the trend line equation (which should be a 5th order polynomial).

-------------------

This time, I cannot solve question (C).

I can only calculate the part of CSTR.

For the PER in case (1):

(1000/60)(5.0244) (5.0244 is the area that from xA=0 to 0.230769, 1000/60 is the flow rate from part (B))
=83.74L

My answer is wrong, but I don't know what's wrong with my calculation

3arZ9.jpg
 
Last edited:
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Are you sure about your data? I have the same textbook, and mine says 0.045 and 0.042 for the last two values of r
 
Oh, thank you for reminding me. because I don't have the textbook.
But, I still cannot find out the answer after using the right value.
Is it wrong for me to plot a graph?
 
I don't think there is anything wrong with fitting the data to a line and then integrating from 0.3 to 1.3 (which is one method that the hint does suggest), however i think it would be easier to just integrate numerically with approximating sums. Keep in mind that different methods will give different answers (my solution manual says 12.75 minutes).
 

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