Yeah your working is generally fine.
You can assign q4 a value, but it doesn't matter since it is a common factor throughout the whole equation. So what you do is you divide the LHS and RHS of your equation by q4. This leaves:
[tex]\frac {kq_4q_1} {q_4 (r_1_4)^2} - \frac {kq_4q_2} {q_4 (r_2_4)^2} + \frac {kq_4q_3} {q_4(r_3_4)^2} = 0/q4[/tex]
ie [tex]\frac {kq_1} {(r_1_4)^2} - \frac {kq_2} {(r_2_4)^2} + \frac {kq_3} {(r_3_4)^2} = 0[/tex]
Anyway even doing it your way you should have got the same value as me, but you didn't. I got something closer to -4*10^-5 C (this isn't the answer). The actual answer is slighty more than -4*10^-5 C. So you must have made a simple calculating error.