How Do You Derive Expectation Values Using Bra-Ket Notation?

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Homework Help Overview

The discussion revolves around deriving expectation values using bra-ket notation in quantum mechanics. Participants explore the mathematical framework involving operators, eigenvalues, and eigenvectors, particularly focusing on the expression for expectation values.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • Participants discuss the derivation of expectation values, questioning the relationship between the state vector and the operator. There are inquiries about the completeness of eigenvectors and the implications of using the identity operator. Some participants express confusion regarding the operations involved in the derivation and the properties of bra-ket notation.

Discussion Status

The discussion is active, with participants providing hints and partial clarifications regarding the derivation process. Some have expressed understanding of certain concepts, while others continue to seek clarification on specific points, indicating a mix of comprehension and uncertainty.

Contextual Notes

Participants are navigating the complexities of quantum mechanics notation and the implications of various mathematical operations, with some expressing concerns about the clarity of certain identities and operations in bra-ket notation.

The Eggman
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Concerning expectation values...

Also, the derivation in terms of bra-ket rather than wage function would be appreciated.

Where [tex]\psi[/tex] is the system state

Knowing that <A>[tex]\psi[/tex]=<[tex]\psi[/tex]|A|[tex]\psi[/tex]>

And A is comprised of a complete eigenvector set [tex]\phi[/tex]j w/ corresponding eigenvalues aj

How do you derive <A>[tex]\psi[/tex]=[tex]\sum[/tex]aj|<[tex]\psi[/tex]|[tex]\phi[/tex]j>|^2 ?

Additionally, (unrelated to above)

if |[tex]\psi[/tex]> is comprised of component states |[tex]\phi[/tex]>,

And <[tex]\phi[/tex]|[tex]\psi[/tex]>=the relevant expansion coefficient (probability)

What is the value of <[tex]\psi[/tex]|[tex]\phi[/tex]>? The complex conjugate of the expansion coefficient?

Thanks!

http://en.wikipedia.org/wiki/Expectation_value_(quantum_mechanics )
 
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If A has a complete set of eigenvectors [tex]\phi_j[/tex] with eigenvalues [tex]a_j[/tex] then we can write:

[tex]A=\sum_j a_j|\phi_j><\phi_j|[/tex]

So thus <[tex]\psi[/tex]|A|[tex]\psi[/tex]>=[tex]\sum_j a_j<\psi|\phi_j><\phi_j|\psi>=\sum_j a_j<\psi|\phi_j>(<\psi|\phi_j>)^*=\sum_j a_j|<\psi|\phi_j>|^2[/tex]
 
If you're wondering where the first identity comes from then I'll give you a hint:

By completeness: [tex] 1=\sum_j |\phi_j><\phi_j|[/tex]
 
Sorry, I still don't totally understand the first identity. How do you derive that? There isn't a scalar product, so is some other operation implicit?

Also, (this is going to be a stupid question) but |[tex]\phi[/tex]j><[tex]\phi[/tex]j| cannot be simplified, right?Lastly, can you commute the bra and the ket to form a scalar product by taking it's complex conjugate? ( <[tex]\phi[/tex]j|[tex]\phi[/tex]j>*)?

Thanks in advance!
 
Oh wait, did you just use the Identity operator? I think I get it now...
 
The Eggman said:
Oh wait, did you just use the Identity operator? I think I get it now...

Yes exactly, it's just the identity operator. And no you can't commute the bra and the ket because <[tex]\phi[/tex]|[tex]\phi[/tex]>*=<[tex]\phi[/tex]|[tex]\phi[/tex]>
 

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