The matrix $A$ has the interesting property that its square is minus the identity matrix: $A^2 = \begin{bmatrix}-1&0\\0&-1\end{bmatrix}$. That suggests that it should correspond to the complex number $i$.
In fact, $K$ consists of all matrices of the form $\begin{bmatrix}a&-b\\b&a\end{bmatrix}$ where $a$ and $b$ are real numbers. To prove that $K$ is isomorphic to $\Bbb C$ you should show that the map taking $\begin{bmatrix}a&-b\\b&a\end{bmatrix}$ to $a+ib$ is an isomorphism. That is, it is a bijective map that preserves addition and multiplication.