How Does Magnetic Moment Change with Temperature and Field Strength?

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Homework Help Overview

The discussion revolves around finding the magnetic moment of a crystal under varying conditions of temperature and magnetic field strength, specifically in weak fields at high temperatures and strong fields at low temperatures.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning

Approaches and Questions Raised

  • The original poster attempts to analyze the behavior of hyperbolic functions in the context of the magnetic moment as temperature and field strength change. Some participants suggest expressing hyperbolic functions in terms of exponentials to facilitate understanding of the limits involved.

Discussion Status

Participants are exploring the implications of their findings regarding the magnetic moment in different regimes. Some guidance has been offered regarding the interpretation of results, particularly in relation to the Curie law at high temperatures and the occupation of ground states at low temperatures.

Contextual Notes

Assumptions about the paramagnetic nature of the crystal are noted, and there is an emphasis on the limits of the hyperbolic functions as they relate to the physical conditions described.

patrickmoloney
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Homework Statement


Find the magnetic moment of a crystal when placed

(i) in a weak field at high temperature

(ii) in a strong field at low temperature

Homework Equations



This is the last part of a question which I feel I have solved correctly up until this point.

The mean magnetic moment I found is

\langle M \rangle = N_{\mu} \frac{2 \sinh \Big{(}\dfrac{\mu \beta}{kT}\Big{)}}{1+ \cosh \Big{(}\dfrac{\mu \beta}{kT}\Big{)}}

The Attempt at a Solution



Well at high temperature and low magnetic field strength

\dfrac{\mu \beta}{kT} \ll 1

And at low temperature high magnetic field strength

\dfrac{\mu \beta}{kT} \gg 1

What happens to the hyperbolic functions as one goes to 0 and one goes to \infty?

EDIT: I know what happens as \lim_{x \rightarrow \infty}\sinh x = e^x and \lim_{x \rightarrow \infty}\cosh x = e^x
 
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I assume your crystal is paramagnetic. You might see what's going more easily if you cast the hyperbolic functions in terms of exponentials, then take the limits.
 
(i)Weak field at high temperature

\dfrac{\mu B}{kT} \ll 1 \implies e^{\frac{\mu B}{kT}} \approx 1 \pm \dfrac{\mu B}{kT}

From my mean magnetic momentM= N\mu \dfrac{e^{\frac{\mu B}{kT}}-e^{\frac{\mu B}{kT}}}{1 + e^{-\frac{\mu B}{kT}} + e^{\frac{\mu B}{kT}}}

substituting e^{\frac{\mu B}{kT}} = 1 \pm \dfrac{\mu B}{kT}

M = \dfrac{1+\frac{\mu B}{kT} -1 + \frac{\mu B}{kT}}{1+1-\frac{\mu B}{kT} + 1 + \frac{\mu B}{KT}} = \dfrac{2N\mu^2 B}{3kT}

(ii) Strong field at low temperature

\dfrac{\mu B}{kT} \gg 1 \implies e^{\frac{\mu B}{kT}} \gg 1 \pm e^{-\frac{\mu B}{kT}} \gg 1

Hence

M= N\mu \dfrac{e^{\frac{\mu B}{kT}}}{e^{\frac{\mu B}{kT}}}= N\mu
 
Looks right. At the high temperature end you get the 1/T Curie law dependence. At low temperature, only (mostly) the ground state is occupied and the magnetization is the number of magnetic moments times the value of one moment.
 
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kuruman said:
Looks right. At the high temperature end you get the 1/T Curie law dependence. At low temperature, only (mostly) the ground state is occupied and the magnetization is the number of magnetic moments times the value of one moment.
Much appreciated. Insight into these types of problems helps a lot. Thanks
 

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