How high can an airship rise?

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Airships rise until their average density equals that of the surrounding atmosphere, at which point they stop gaining altitude. The pressure inside the airship's lifting gas plays a critical role in buoyancy, as a higher internal pressure compared to the outside generates lift. Releasing gas to equalize pressure does not make the airship lighter; instead, it reduces volume, causing it to sink. The design of the gas bags influences how pressure changes with altitude, with flexible bags allowing for expansion and maintaining lift. Ultimately, achieving higher altitudes requires careful management of gas density and pressure differences.
  • #31
askingask said:
Can you reference any video or article to read? Keep in mind I’m just an undergrad.
The best way to understand LTA craft is with the case of a hot air balloon.


askingask said:
Are you telling me that baluncore is overcomplicating this entire thing to confuse me
askingask said:
Is the pressure inside the airship the main factor which makes the whole airship heavier compared to the low pressure atmosphere?
And would releasing gas from the airship, to neutralize pressure differences, make the airship lighter again compared to the air it displaces?
You are confusing yourself by talking about the pressure of hydrogen inside the bag, and the external atmosphere, without realising that the pressures are height and density specific, so you need to consider the differential hydrostatic pressures over the whole of the envelope.

An LTA craft, hangs from bags of lifting gas, in way similar to how a bicycle hangs from its wheel spokes.
 
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  • #32
hutchphd said:
No that is very far from what I said. Please pay careful attention.
You are assuming that you are "correct" and that he is therefore "wrong" (or confusing0 In fact try to see that you are each using different words to describe the same essrntially correct physics. Actual physics is done using mathematics for this very reason.w
No that is in turn not what I said. I thought my whole understanding of buoyancy was wrong, that is why. Though this meta stuff is irrelevant to the Forum I guess.
 
  • #33
Baluncore said:
without realising that the pressures are height and density specific, so you need to consider the differential hydrostatic pressures over the whole of the envelope.
I finally understand what you mean, thank you, though I‘ll probably do a bit of research to this, but thanks for the video.
 
  • #34
The OP's question, I think, calls for a hypothetical envelope of volume V and mass M that is perfectly rigid and thus maintains constant volume. Fill this vehicle with one atm. of helium at sea level, and turn it loose. As it rises, the external pressure drops. Releasing helium will indeed reduce the mass of the vehicle, and reduce its density, allowing it to rise higher. If the mass of the contained helium at any given altitude is m, the limit on altitude will be the height at which the density of the vehicle, (M+m)/V, equals the density of the atmosphere at that same given altitude. (Scientific high-altitude balloons will get to this height before bursting, where V is the mechanical limit on the volume of the envelope.)
You could get a bit higher if you evacuated this (extremely) theoretical envelope, leaving a high vacuum, before releasing the vehicle. Since m=0, this "vacuum balloon" would rise to the point where the atmosphere has density M/V.
 
  • #35
James Demers said:
The OP's question, I think, calls for a hypothetical envelope of volume V and mass M that is perfectly rigid and thus maintains constant volume. Fill this vehicle with one atm. of helium at sea level, and turn it loose. As it rises, the external pressure drops. Releasing helium will indeed reduce the mass of the vehicle, and reduce its density, allowing it to rise higher. If the mass of the contained helium at any given altitude is m, the limit on altitude will be the height at which the density of the vehicle, (M+m)/V, equals the density of the atmosphere at that same given altitude. (Scientific high-altitude balloons will get to this height before bursting, where V is the mechanical limit on the volume of the envelope.)
You could get a bit higher if you evacuated this (extremely) theoretical envelope, leaving a high vacuum, before releasing the vehicle. Since m=0, this "vacuum balloon" would rise to the point where the atmosphere has density M/V.
This is exactly what I asked for. Thank you.
 
  • #36
There are some changes that need to happen, to take the thought experiment towards a real experiment.

James Demers said:
a hypothetical envelope of volume V and mass M that is perfectly rigid and thus maintains constant volume.
Using a sphere of the lightest weight film would weigh less and still limit the volume. Also, the top of the envelope needs thicker film to withstand greater differential pressure and surface tension, than at the bottom, where thinner film can be used. That film mass distribution will tend to capsize the balloon, unless there is a suspended payload that defines the base of the envelope.

James Demers said:
Fill this vehicle with one atm. of helium at sea level, and turn it loose.
A film envelope will lift with only about 10% hydrogen or helium. Why waste the limited helium resource, by 100% filling a rigid envelope, when a spherical film envelope is easier to transport and costs 90% less to partially fill?

James Demers said:
As it rises, the external pressure drops. Releasing helium will indeed reduce the mass of the vehicle, and reduce its density, allowing it to rise higher.
As it rises, a film envelope will expand with the lift gas, until finally, the base of the film envelope becomes spherical. Then the mode of operation changes. I would put a one-way flap valve at the base to release the excess lift gas, so there is zero differential pressure pushing the base of the envelope downwards from inside.

James Demers said:
Scientific high-altitude balloons will get to this height before bursting, where V is the mechanical limit on the volume of the envelope.
Bursting is used to aid recovery of the payload, and to clear the controlled airspace. By continuously venting excess lift gas from an opening in the base, a greater height than the burst height would be reached.
 
  • #37
James Demers said:
You could get a bit higher if you evacuated this (extremely) theoretical envelope, leaving a high vacuum, before releasing the vehicle.
Consider a rigid spherical envelope, that you want to fly as a vacuum balloon, to a height where the external air pressure is; Pa.

Initially, on the ground, the envelope is manufactured, filled with air at one bar.
Start pumping out air, until the internal pressure is Pa below local atmospheric.
The balloon will then start to lift, with only a partial vacuum.
The envelope then only needs to withstand an external crush of Pa.
The internal depression of Pa, reduces the density of the internal air.
No special, rare or expensive lifting gas is needed.

As the balloon rises, pump out more air, maintaining a differential pressure of Pa.
When the balloon has reached an altitude where the external air pressure is Pa, the envelope will contain a true vacuum.

At no time during the flight was the external crush greater than Pa.
The (solar powered) pump never needed to develop a pressure difference greater than Pa.

The big mistake with vacuum balloons, is attempting to design them to withstand the crush of a high vacuum at sea level.
 
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  • #38
Baluncore said:
Consider a rigid spherical envelope, that you want to fly as a vacuum balloon, to a height where the external air pressure is; Pa.

Initially, on the ground, the envelope is manufactured, filled with air at one bar.
Start pumping out air, until the internal pressure is Pa below local atmospheric.
The balloon will then start to lift, with only a partial vacuum.
The envelope then only needs to withstand an external crush of Pa.
The internal depression of Pa, reduces the density of the internal air.
No special, rare or expensive lifting gas is needed.

As the balloon rises, pump out more air, maintaining a differential pressure of Pa.
When the balloon has reached an altitude where the external air pressure is Pa, the envelope will contain a true vacuum.

At no time during the flight was the external crush greater than Pa.
The (solar powered) pump never needed to develop a pressure difference greater than Pa.

The big mistake with vacuum balloons, is attempting to design them to withstand the crush of a high vacuum at sea level.
That is genius, never thought about that, but based on our discussion here, it makes absolutely sense. The only problem here is that to keep the envelop lightweight the pressure difference has to be small. But if the pressure difference is small net buoyancy will also be very small. Question is where is the optimal point, if one exists even, where the weight of the envelop is small enough and the pressure difference is big enough to ensure the density difference.
 
  • #39
Baluncore said:
Consider a rigid spherical envelope, that you want to fly as a vacuum balloon, to a height where the external air pressure is; Pa.

Initially, on the ground, the envelope is manufactured, filled with air at one bar.
Start pumping out air, until the internal pressure is Pa below local atmospheric.
The balloon will then start to lift, with only a partial vacuum.
The envelope then only needs to withstand an external crush of Pa.
The internal depression of Pa, reduces the density of the internal air.
No special, rare or expensive lifting gas is needed.

As the balloon rises, pump out more air, maintaining a differential pressure of Pa.
When the balloon has reached an altitude where the external air pressure is Pa, the envelope will contain a true vacuum.

At no time during the flight was the external crush greater than Pa.
The (solar powered) pump never needed to develop a pressure difference greater than Pa.

The big mistake with vacuum balloons, is attempting to design them to withstand the crush of a high vacuum at sea level.
Perhaps this could be especially useful for missions on mars.
 
  • #40
askingask said:
The only problem here is that to keep the envelop lightweight the pressure difference has to be small. But if the pressure difference is small net buoyancy will also be very small.
A functional vacuum balloon does not yet exist, because a sufficiently low-mass, crush-surviving envelope, has still not been engineered. But, I expect it will happen.
 
  • #41
Baluncore said:
A functional vacuum balloon does not yet exist, because a sufficiently low-mass, crush-surviving envelope, has still not been engineered. But, I expect it will happen.
Honestly hydrogen is pretty good already and people over estimate its danger. No need for expensive helium.
 
  • #42
askingask said:
Honestly hydrogen is pretty good already and people over estimate its danger.
If you use hydrogen, the cost of insurance will be greater for historical reasons.
Hydrogen molecules are small, fast, and pass through many envelope materials. Helium diffuses at a lower rate.
 
  • #43
Baluncore said:
for historical reasons.
Lol
 
  • #44
Baluncore said:
The big mistake with vacuum balloons, is attempting to design them to withstand the crush of a high vacuum at sea level.
I respectfully disagree. If the pressure difference between exterior and interior of the vacuum balloon is small, the shell needs to be very light to provide buoyancy, so it would be more difficult to prevent the balloon failure, in spite of the lesser pressure difference. According to our calculations/computations, it is easier to design a vacuum balloon for sea level and low interior pressure / high pressure difference than, say, for sea level and low pressure difference, or for higher altitudes.

We offered a design of a sea level and high pressure difference vacuum balloon at Eng 2021, 2(4), 480-491
 
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  • #45
akhmeteli said:
According to our calculations/computations, it is easier to design a vacuum balloon for sea level and low interior pressure / high pressure difference than, say, for sea level and low pressure difference, or for higher altitudes.
That is true, but to rise to any altitude where the air pressure is Pa, the balloon must also be neutrally buoyant, with a differential envelope pressure of Pa, at sea level. I ask why a high vacuum would be needed at sea level, if that design will later fly at an external pressure of Pa.

A demonstration system, capable of neutral buoyancy at sea level with high vacuum, would be unable to rise above sea level.

That challenge has the same design and material constraints, as if you halve the mass of the carcass, at half an atmosphere differential pressure, with half the crush, and the balloon could rise from sea level to half an atmosphere = 5470 metres.

The limiting factor is the composite materials needed, and the composite structures required for both tension and compression, to prevent the crush.

I predict the first partial-vacuum balloon to fly will be in a hot and dry atmosphere. There should be a few drops of water inside the balloon, so the RH of the internal air, remains close to 100%, or would that be cheating?
 
  • #46
Baluncore said:
That is true, but to rise to any altitude where the air pressure is Pa, the balloon must also be neutrally buoyant, with a differential envelope pressure of Pa, at sea level. I ask why a high vacuum would be needed at sea level, if that design will later fly at an external pressure of Pa.
But vacuum balloons can have some applications at sea level as well, so I don't understand why designing vacuum balloons for sea level would be a "big mistake".
Baluncore said:
A demonstration system, capable of neutral buoyancy at sea level with high vacuum, would be unable to rise above sea level.
Technically, yes, but, for example, at the altitude of 150 m, the air density is just 1.8% less than that at sea level (and the pressure is about 1.8% less), so a system designed for a range from 0 m to 150 m will not be much different from a purely sea level system. On the other hand, the distance of direct vision at the altitude of 150 m is about 44 km, so this altitude may be of interest, say, for antenna applications.
Baluncore said:
I predict the first partial-vacuum balloon to fly will be in a hot and dry atmosphere. There should be a few drops of water inside the balloon, so the RH of the internal air, remains close to 100%, or would that be cheating?
I have not thought about "dry", but cold air is better for a vacuum balloon. The pressure being equal, the buoyancy force is higher for cold air as air density is higher.
 
  • #47
akhmeteli said:
The pressure being equal, the buoyancy force is higher for cold air as air density is higher.
The temperature of a partial-vacuum balloon will equilibrate with the environment. The saturated air, inside the balloon, will have a lower density than the dry air outside. That is significantly enhanced at higher temperatures.
 
  • #48
Baluncore said:
The temperature of a partial-vacuum balloon will equilibrate with the environment. The saturated air, inside the balloon, will have a lower density than the dry air outside. That is significantly enhanced at higher temperatures.
At high altitudes, there cannot be "hot atmosphere" (unless one considers altitudes unreasonable for balloons). As for sea level, let us compare temperatures of 0 deg C and 50 deg C. The pressure of saturated vapor pressure at 50C is about 12% of the atmospheric pressure, but the air density and, therefore, the buoyancy force is about 15% less at 50C than at 0C (for the same atmospheric pressure).
 
  • #49
akhmeteli said:
On the other hand, the distance of direct vision at the altitude of 150 m is about 44 km, so this altitude may be of interest, say, for antenna applications.
At 150 metres you could use a fixed tower, or a tethered helium balloon. I have flown gyro kites well above 150 m, and they generate their own power.

akhmeteli said:
At high altitudes, there cannot be "hot atmosphere" (unless one considers altitudes unreasonable for balloons).
A high-vacuum balloon at sea level is a demonstration package, of less practical use than a stepladder. It will hover best below sea level, on a cold and dry night, during an anticyclone. Think the Dead Sea, Death Valley, or deep underground in a mine. The problem with mines is that they get hotter with depth, and have RH=100%.

Only a partial-vacuum balloon can benefit from internal saturation, RH=100%. At the depressed boiling point of water, the lift gas remaining would be steam from the air, being a clear cloud chamber.
 
  • #50
Baluncore said:
At 150 metres you could use a fixed tower, or a tethered helium balloon. I have flown gyro kites well above 150 m, and they generate their own power.
Fixed towers of this height are (very?) expensive, they require some land to own or rent, they require lighting for aircraft safety, which creates serious maintenance problems.

As for helium balloons, they have their own set of issues (don't get me started:-) ). Furthermore, helium balloons are competitors to stratospheric vacuum balloons too.

I don't know much about gyro kites, but I believe they are wind-dependent.

And tethered balloons require some real estate, and their altitude is wind-dependent
Baluncore said:
A high-vacuum balloon at sea level is a demonstration package, of less practical use than a stepladder. It will hover best below sea level, on a cold and dry night, during an anticyclone. Think the Dead Sea, Death Valley, or deep underground in a mine. The problem with mines is that they get hotter with depth, and have RH=100%.
So you don't think there is any application for low-altitude vacuum balloons. I believe there are some important applications, such as antennas, freight transportation in remote areas, etc., so let us agree to disagree.

And let us not forget that, while making a sea-level balloon is really hard, making a stratospheric balloon is significantly harder.
Baluncore said:
Only a partial-vacuum balloon can benefit from internal saturation, RH=100%. At the depressed boiling point of water, the lift gas remaining would be steam from the air, being a clear cloud chamber.
So again, internal saturation does not seem important at low altitudes, and temperature and water vapor content are low at high altitudes.
 
  • #51
akhmeteli said:
As for helium balloons, they have their own set of issues (don't get me started:-) ). Furthermore, helium balloons are competitors to stratospheric vacuum balloons too.
Only one competitor wins each race. I will bet on the favourite, helium. Vacuum balloons have so many issues, they DNS.

akhmeteli said:
I don't know much about gyro kites, but I believe they are wind-dependent.
They can be flown from a slow moving vehicle or a ship. The vehicle can stop when there is some wind.

akhmeteli said:
And tethered balloons require some real estate, and their altitude is wind-dependent
Untethered balloons do not stay where you release them. Their position is wind dependent, unless they are dirigible.

akhmeteli said:
So you don't think there is any application for low-altitude vacuum balloons. I believe there are some important applications, such as antennas, freight transportation in remote areas, etc., so let us agree to disagree.
We have not needed vacuum balloons for those applications before. Instead, we have used lifting gas balloons, that are more available and less fragile than vacuum balloons. I have no problem disagreeing with you on the existence of applications for vacuum balloons. Vacuum balloons will be a novelty, with no application that cannot be met by a helium balloon.

akhmeteli said:
And let us not forget that, while making a sea-level balloon is really hard, making a stratospheric balloon is significantly harder.
There are several companies making and flying stratospheric balloons now, so how hard can hard be? I believe it is hard to make a vacuum balloon, even for sea level.

akhmeteli said:
So again, internal saturation does not seem important at low altitudes, and temperature and water vapor content are low at high altitudes.
Internal saturation is important at low altitudes. The molecular weight of dry air is 29 g/mole, while that of water is 18 g/mole. That becomes important at low altitudes and high temperatures. When low RH increases the density of the external air, the presence of saturated air inside the balloon, becomes an advantage. That is obviously not possible with a vacuum balloon.
 
  • #52
askingask said:
Now let us say we have some form of non elastic gasbag filled with hydrogen. Just for simplicity sake. I'm not asking for the material weight of that bag or whatever. All I'm asking for, is that if the bag rises to an altitude where it can't go any higher. Would venting the gas of the bag to equalize pressure, compared to the atmosphere at that altitude, cause the bag to gain altitude again?
I was away for the weekend and only skimmed the rest of the posts...

The gas bags of most balloons are already non-elastic. Do you mean fixed volume? Rigid? Or having more gas than needed for the volume and lift? If the last, then yes. In other words, the balloon gains altitude until fully inflated and keeps gaining altitude until the outside air density is low enough that the balloon can't rise any further(or it pops). If the internal pressure at that point is above atmospheric then it can vent lifting gas and rise a little further. But not as much as if it had a larger envelope.

...I don't know what you're actually looking for here though.
 
Last edited:
  • #53
russ_watters said:
If the internal pressure at that point is above atmospheric then it can vent lifting gas and rise a little further.
And that lift-gas venting, should be done from the lowest point of the envelope, where the optimum differential pressure is zero.
 
  • #54
Baluncore said:
And that lift-gas venting, should be done from the lowest point of the envelope, where the optimum differential pressure is zero.
Deleted a prior reply...I'm not sure I care to get into these intricacies without knowing which scenario the OP is after. There's a lot of nuance here that I don't think matters to OP, and answers that are scenario-dependent.
 
  • #55
Baluncore said:
Only one competitor wins each race. I will bet on the favourite, helium. Vacuum balloons have so many issues, they DNS.
There is a difference between "helium is the winner of the race" and "low-altitude vacuum balloons do not have applications"
Baluncore said:
They can be flown from a slow moving vehicle or a ship. The vehicle can stop when there is some wind.
That makes them an exotic solution even in the best-case scenario.
Baluncore said:
Untethered balloons do not stay where you release them. Their position is wind dependent, unless they are dirigible.
I agree, but this is true both for low- and high-altitude vacuum balloons (and for helium balloons).
Baluncore said:
We have not needed vacuum balloons for those applications before. Instead, we have used lifting gas balloons, that are more available and less fragile than vacuum balloons. I have no problem disagreeing with you on the existence of applications for vacuum balloons. Vacuum balloons will be a novelty, with no application that cannot be met by a helium balloon.
Note that helium balloons have difficulty with altitude control. For example, if they are used for freight transportation, they need to get some ballast onboard after unloading to get rid of excessive buoyancy (or require helium compression). Vacuum balloons can just bleed in some air.
Baluncore said:
There are several companies making and flying stratospheric balloons now, so how hard can hard be? I believe it is hard to make a vacuum balloon, even for sea level.
Sorry, I meant to say "And let us not forget that, while making a sea-level vacuum balloon is really hard, making a stratospheric vacuum balloon is significantly harder."
Baluncore said:
Internal saturation is important at low altitudes. The molecular weight of dry air is 29 g/mole, while that of water is 18 g/mole. That becomes important at low altitudes and high temperatures. When low RH increases the density of the external air, the presence of saturated air inside the balloon, becomes an advantage. That is obviously not possible with a vacuum balloon.
I am not sure about that. My understanding is water vapor can exist in vacuum as well, depending on the wall temperature.
 
  • #56
akhmeteli said:
There is a difference between "helium is the winner of the race" and "low-altitude vacuum balloons do not have applications"
That there is a difference is a truism, and both statements are true.
akhmeteli said:
That makes them an exotic solution even in the best-case scenario.
Gyro kites have filled some observation and antenna applications since the 1940s.
https://en.wikipedia.org/wiki/Rotor_kite
Any balloon has drag, so is pulled down in a wind, or when towed by a vehicle. Kites fly higher than balloons in a wind, gyro kites fly higher than traditional kites. Gyro kites are practical, and certainly not as exotic as vacuum balloons.

akhmeteli said:
Note that helium balloons have difficulty with altitude control. For example, if they are used for freight transportation, they need to get some ballast onboard after unloading to get rid of excessive buoyancy (or require helium compression). Vacuum balloons can just bleed in some air.
I have more difficulty with understanding, how a load can possibly be attached to the envelope of a vacuum balloon, without catastrophically destroying the symmetry of balanced forces.
Where a payload is delivered, a prepared ballast load can be collected.

akhmeteli said:
"And let us not forget that, while making a sea-level vacuum balloon is really hard, making a stratospheric vacuum balloon is significantly harder."
How do you support a sea level vacuum balloon during construction and liftoff?
A partial vacuum balloon for high altitude flight can move through the entire process.

akhmeteli said:
I am not sure about that. My understanding is water vapor can exist in vacuum as well, depending on the wall temperature.
In a partial vacuum, yes, but not in a true or full vacuum. Water molecules may stick chemically to the cold wall of a vacuum chamber, but not in sufficient numbers to create lift.
 
  • #57
russ_watters said:
Deleted a prior reply...I'm not sure I care to get into these intricacies without knowing which scenario the OP is after. There's a lot of nuance here that I don't think matters to OP, and answers that are scenario-dependent.
It has been answered by James Demers already. But thank you.
 
  • #58
Baluncore said:
That there is a difference is a truism, and both statements are true.
At least the second statement is just your opinion.
Baluncore said:
Gyro kites have filled some observation and antenna applications since the 1940s.
https://en.wikipedia.org/wiki/Rotor_kite
Any balloon has drag, so is pulled down in a wind, or when towed by a vehicle. Kites fly higher than balloons in a wind, gyro kites fly higher than traditional kites. Gyro kites are practical, and certainly not as exotic as vacuum balloons.
I used "exotic" for versions towed by vehicles, which require vehicles, roads, and what not.
Baluncore said:
I have more difficulty with understanding, how a load can possibly be attached to the envelope of a vacuum balloon, without catastrophically destroying the symmetry of balanced forces.
Where a payload is delivered, a prepared ballast load can be collected.
Let us consider a numerical example. Let us assume that the vacuum balloon has the radius of R=2.5 m, the air density is \rho=1.29 kg/m3. The maximum lift it can create (if we neglect the mass of the shell:-) ) is (4/3)\pi R^3\rho\approx 84 kg, whereas the force of atmospheric pressure acting on 1 square meter of the surfaced of the balloon is about 10 tons, i.e., more than a hundred times greater. So I don't see the load "catastrophically destroying the symmetry of balanced forces". As for attaching a load to a vacuum balloon, one can use a thin film enveloping the balloon and attach the load to this film under the balloon (the film will have a shape of a pear with the thinner end at the bottom).
Baluncore said:
How do you support a sea level vacuum balloon during construction and liftoff?
A partial vacuum balloon for high altitude flight can move through the entire process.
For example, using a light plastic foam support concave at the top or a similar inflated support.
Baluncore said:
In a partial vacuum, yes, but not in a true or full vacuum. Water molecules may stick chemically to the cold wall of a vacuum chamber, but not in sufficient numbers to create lift.
I don't understand that. Water molecules stuck to the cold wall of a vacuum chamber do not create lift or internal pressure.
 
  • #59
akhmeteli said:
My understanding is water vapor can exist in vacuum as well, depending on the wall temperature.
Obviously, if there is water vapour present, then it is not a true vacuum. To be a true vacuum, any water molecules present would have to chemically bond to the cold wall of the chamber, increasing the mass of the envelope.

akhmeteli said:
I don't understand that. Water molecules stuck to the cold wall of a vacuum chamber do not create lift or internal pressure.
I did not say that they did. You hypothesised a belief in a contradiction, where there was a true vacuum containing free water vapour. You have now gone off on a tangent.

Water boils at lower temperatures, at lower pressures. A partial-vacuum balloon can contain cold steam, without other air molecules being present.
In a partial-vacuum balloon, where the air is replaced by water vapour, the balloon has greater buoyancy than with the same internal pressure of dry air.
The advantage of water vapour over dry air is; 29 / 18 = 1.6
Obviously, that advantage is not available with a full-vacuum balloon.
 
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  • #60
Baluncore said:
Obviously, if there is water vapour present, then it is not a true vacuum. To be a true vacuum, any water molecules present would have to chemically bond to the cold wall of the chamber, increasing the mass of the envelope.
Technically, yes, but there is such thing as Torricellian vacuum. There can be water vapor and nothing else in a container.
Baluncore said:
I did not say that they did. You hypothesised a belief in a contradiction, where there was a true vacuum containing free water vapour. You have now gone off on a tangent.
Again, there can be water vapor and nothing else in a container. But I'd say you went off on a tangent when you started to talk about humidity. Condensation makes water vapor impractical as lighter-than-air gas for Earth atmosphere.
Baluncore said:
Water boils at lower temperatures, at lower pressures. A partial-vacuum balloon can contain cold steam, without other air molecules being present.
In a partial-vacuum balloon, where the air is replaced by water vapour, the balloon has greater buoyancy than with the same internal pressure of dry air.
The advantage of water vapour over dry air is; 29 / 18 = 1.6
Obviously, that advantage is not available with a full-vacuum balloon.
Again, technically, yes, but if "the air is replaced by water vapour", it is Torricellian vacuum. And again, I don't think water vapor can be practical as a lighter-than-air gas in Earth atmosphere due to condensation at reasonable temperatures.
 

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