How is the angle of BF3 120 degrees?

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SUMMARY

The bond angle of boron trifluoride (BF3) is definitively 120 degrees due to its trigonal planar structure resulting from sp2 hybridization. Despite the presence of back bonding, which can influence bond angles, it does not lead to an increase in the bond angle beyond the predicted 120 degrees. The discussion highlights that any increase in bond angles for all three fluorine atoms is not feasible within the molecular geometry of BF3.

PREREQUISITES
  • Understanding of molecular geometry and hybridization, specifically sp2 hybridization.
  • Knowledge of bond angles in trigonal planar structures.
  • Familiarity with the concept of back bonding in molecular chemistry.
  • Basic grasp of the properties of boron trifluoride (BF3) and its electronic structure.
NEXT STEPS
  • Research the effects of back bonding on molecular geometry in other compounds.
  • Study the hybridization of other trigonal planar molecules, such as sulfur trioxide (SO3).
  • Explore the concept of bond angles in various molecular geometries, focusing on deviations from ideal angles.
  • Investigate the role of electronegativity in bond angles and molecular shape.
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Chemistry students, molecular modelers, and educators seeking to deepen their understanding of molecular geometry and hybridization effects in compounds like BF3.

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Since it shows back bonding, shouldn't it be a little more than that?
 
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jim mcnamara said:
Thanks but I've already been there.
My query was that BF3 already has trigonal planar structure by hybridization. And the predicted bond angle is 120 deg.
But, we know that it shows BB too. So why doesn't it increases the bond angle?
 
Which bond angle? all three? Is that possible?
 
prakhargupta3301 said:
So why doesn't it increases the bond angle?
What number would it increase to?

Edit: ninja'd by mjc123
 
TeethWhitener said:
What number would it increase to?
mjc123 said:
Which bond angle? all three? Is that possible?

Edit: ninja'd by mjc123
Um. I don't know.
Perhaps that answered my question. An increase in all three is just impossible. Perhaps I was only playing around with the idea of BB with just one F but it's with all three. Is that what you mean?
 
prakhargupta3301 said:
An increase in all three is just impossible.
prakhargupta3301 said:
Is that what you mean?
Yes (I can't speak for mjc, but that's what I was thinking)
 
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TeethWhitener said:
Yes (I can't speak for mjc, but that's what I was thinking)
Okay thanks for helping me!
 

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