How are angles in molecules calculated?

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Discussion Overview

The discussion revolves around the calculation of bond angles in molecules, specifically focusing on compounds with four bonds, such as methane. Participants explore the reasoning behind the bond angles and how they are determined for various molecular geometries, including those with lone pairs of electrons.

Discussion Character

  • Exploratory
  • Technical explanation
  • Debate/contested

Main Points Raised

  • One participant expresses understanding of bond angles for atoms with 2, 3, 5, and 6 bonds but seeks clarification on the specific case of methane, where the H-C-H angle is 109.5°.
  • Several participants request elaboration on the differences in calculating angles for methane compared to other molecules.
  • Another participant questions the reasoning behind the bond angles for water and other molecules with varying numbers of bonds and lone pairs.
  • One participant cites VSEPR theory, stating that the C-H bonds in methane spread out to achieve a bond angle of 109.5° to minimize repulsion.
  • There is a repeated request for clarification on how angles are calculated for atoms bonded to two or three other atoms.
  • Some participants express confusion about the original question and what specific information is being sought regarding bond angles.

Areas of Agreement / Disagreement

Participants do not reach a consensus on the specific inquiry regarding bond angles in methane, and multiple viewpoints on the clarity of the question and the reasoning behind bond angles remain. The discussion reflects uncertainty and a lack of agreement on the core issue.

Contextual Notes

Participants mention VSEPR theory as a basis for understanding bond angles, but there is no agreement on how the specific angle values are derived or calculated, leaving some assumptions and definitions unresolved.

IDK10
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I understand how angles are calculated in compounds where an atom is bonded to 2, 3, 5, and 6 bonds (bond pair + lone pair). But how do they work out the angle of a compound where an atom has 4 bonds (i.e. methane), in this case the carbon atom, has a H-C-H angle of 109.5°
 
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Please elaborate, I fail to see how it is different.
 
Borek said:
Please elaborate, I fail to see how it is different.
In methane and any other compound containing an atoms which only has 4 bond pairs and 0 lone pairs of electrons. The bond between the three atoms (in the case of methane, it is the H-C-H bond angle), it is 109.5°, I was wondering how they worked that out.
 
And how they worked out the value for water molecule, or for any other molecule with any number of bonds and/or lone pairs?

I don't see why you say you know how to deal with other molecules, but you think this particular molecule is different.
 
Borek said:
And how they worked out the value for water molecule, or for any other molecule with any number of bonds and/or lone pairs?

I don't see why you say you know how to deal with other molecules, but you think this particular molecule is different.
I'm not saying that, I'm asking how they first got the bond angles for an atom with 4 bond pairs, I'm just giving methane as an example.
 
Sorry, I still fail to see where the problem is.

You know how to calculate angle for atom bonded to two other atoms. Can you explain how it is done?

You know how to calculate angle for atom bonded to three other atoms. Can you explain how it is done?
 
Comeback City said:
The C-H bonds want to be as far apart from each other as possible, as is stated by VSEPR, so they spread out to that 109.5 °. If you are asking why it is 109.5, then

We don't know what he is asking. That's what I am trying to find out.
 
Borek said:
We don't know what he is asking. That's what I am trying to find out.
Good call :cool:
 

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