How to Calculate Efficiency of a Van der Waals Gas Cycle?

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SUMMARY

The discussion centers on calculating the efficiency of a Van der Waals gas cycle represented on a temperature-entropy (T-S) diagram. Participants clarify that the cycle is parameterized using T_h and T_c, and efficiency can be derived by integrating the heat transfer equations Q = TdS over the specified curves. A key challenge identified is obtaining an expression for temperature as a function of entropy, particularly due to the differing units of T and S, which complicates the representation of the cycle as a circle on the T-S diagram.

PREREQUISITES
  • Understanding of Van der Waals equation of state
  • Familiarity with thermodynamic concepts such as heat transfer and entropy
  • Proficiency in calculus for integration
  • Knowledge of T-S diagrams and their interpretation
NEXT STEPS
  • Study the derivation of the Van der Waals equation of state
  • Learn how to perform integrals involving thermodynamic equations
  • Research the implications of unit consistency in thermodynamic diagrams
  • Explore methods for calculating efficiency in thermodynamic cycles
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Students and professionals in thermodynamics, particularly those focusing on gas cycles and efficiency calculations, will benefit from this discussion.

TK421
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Homework Statement


n moles of gas, that follow van der Waals equation are to be employed as the auxiliary system in a circular cycle(parameterized using T_h and T_c as shown on the TS diagram. Calculate the efficiency of the cycle.
300px-Carnot_cycle_TS.png

Homework Equations


dd3272a14ad6d40a0c7043c59febef22a36554e3
,
443830ab2a64edf2fbda997450e2e19e637c7849
, Q = TdS

The Attempt at a Solution


Idea is simple. I just divide circle curve horizontally in two two curves. Using Q = TdS , by integration over the top curve i obtain Q_(in), by integrating over the bottom curve i obtain Q_(out). Then i easily get efficiency using equation above. The only problem is, that i don't know, how to calculate those integrals with only van der Waals equation of state initially given.
 

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    300px-Carnot_cycle_TS.png
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What is the equation for the area of an ellipse in terms of the semi major and semi minor axes?
 
Sorry, I wasn't precise enough, it has to be a circle, not an ellipse. I put that diagram more for an illustrative purpose.
 
TK421 said:
Sorry, I wasn't precise enough, it has to be a circle, not an ellipse. I put that diagram more for an illustrative purpose.
How can it be a circle if the units are different? If you change the units of either T or S, the shape changes.
 
Absolutely.
The task itself states, that we are given a cycle, which is represented as a circle on a T-S diagram, which is parameterized using T_h and T_c.
My main concern though is, how would i get an expression of T as a function of S...
 
TK421 said:
Absolutely.
The task itself states, that we are given a cycle, which is represented as a circle on a T-S diagram, which is parameterized using T_h and T_c.
My main concern though is, how would i get an expression of T as a function of S...
$$\left(\frac{T-\frac{(T_H+T_C)}{2}}{\frac{(T_H-T_C)}{2}}\right)^2+\left(\frac{S-\frac{(S_{max}+S_{min})}{2}}{\frac{(S_{max}-S_{min})}{2}}\right)^2=1$$
 
Like I said, since T and S have different units, you can't represent the variation as a circle on a T-S diagram. What don't you understand about this?
 
I do understand it now. Thank you :)
 
TK421 said:
I do understand it now. Thank you :)
So what do you get for the efficiency?
 

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