How to find empirical formula from combustion equation

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SUMMARY

The combustion analysis of thiophene, a carbon-hydrogen-sulfur compound, reveals its empirical formula through the combustion products CO2, H2O, and SO2. A 1.3020g sample produces 2.7244g of CO2, 0.5575g of H2O, and 0.99151g of SO2. The calculated moles of each product are 0.06186 moles of CO2, 0.00309 moles of H2O, and 0.01548 moles of SO2. By determining the percentage composition of carbon, hydrogen, sulfur, and subsequently oxygen, one can derive the empirical formula based on the atomic ratios of these elements.

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Homework Statement


The organic solvent thiophene is a carbon-hydrogen-sulfur compound that makes C02, H20 AND S02 when burned in excess Oxygen. When subject to combustion analysis, a 1.3020g sample makes 2.7244 g CO2, .5575G H20 and .99151 SO2. Find the empirical formula of thiophene


Homework Equations



None?

The Attempt at a Solution




so first i wrote out the combustion

Thiophene + O2 <> CO2+ H20+SO2 but i can't balance it yet


I then found the amount of moles the compunts on the right side


CO2= 2.772g/44.009g/mol = .06186 moles / .00309 ~ 20 mol
H20= .5575g/18.019g/mol= .00309mole / .00309 = 1 mol
SO2=.9915g/64.045g/mol = .01548 mole / .00309 ~5 mol


therefore

Thiophene + O2 <> 20(CO2)+ H20+5(SO2)

\

But I have no idea where to go from here, anyone have any hints?
 
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first try to find the percentage of carbon from CO2 and hydrogen from h20 and sulphur from so2 then calculae percentage of oxygen from it.
now find mole of each element from its percentage .then find its atomic ratio.this would give the value o empirical formula.
 
zainriaz said:
first try to find the percentage of carbon from CO2 and hydrogen from h20 and sulphur from so2 then calculae percentage of oxygen from it.
now find mole of each element from its percentage .then find its atomic ratio.this would give the value o empirical formula.

thank you very much! I get it know :)
 

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