How to use white phosphorus without ignite it?

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SUMMARY

This discussion focuses on the safe handling and application of white phosphorus, particularly in the context of historical friction matches. White phosphorus ignites upon contact with air, necessitating airtight storage and specific mixing techniques to prevent ignition. The conversation references the historical transition from antimony sulfide to white phosphorus in match production, highlighting the need for moisture or inert substances to mitigate flammability. Additionally, the chemoluminescent properties of white phosphorus are explored, emphasizing its use in special effects without combustion.

PREREQUISITES
  • Understanding of white phosphorus chemical properties
  • Knowledge of historical match production techniques
  • Familiarity with chemoluminescence concepts
  • Basic safety protocols for handling hazardous materials
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  • Research the chemical properties and safety measures for handling white phosphorus
  • Explore the historical context of match production and the transition to safer materials
  • Investigate the applications of chemoluminescence in historical and modern contexts
  • Learn about inert substances that can be mixed with flammable materials to reduce ignition risk
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Chemists, historians of technology, safety professionals, and anyone interested in the historical applications and safety measures associated with white phosphorus.

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As long as it is under water it is not in a direct contact with the air, so it doesn't ignite.

From the same wikipedia article:

Lucifers were however quickly replaced after the discovery in 1830 by Frenchman Charles Sauria who substituted the antimony sulfide with white phosphorus.[15] These new phosphorus matches had to be kept in airtight metal boxes but became popular.
 
yeah, but how they mix in match head in the first place?
 
Perhaps they used wet pasta and the phosphorus was exposed when the mix was dried.

Plenty techniques that could be used.
 
Borek said:
As long as it is under water it is not in a direct contact with the air, so it doesn't ignite.
I have another related question that doesn't involve matches.
White phosphorus glows on contact with air. This is a type of chemoluminescence, not fire. The greenish glow of white phosphorus was used for nineteenth century special effects. The chemoluminescence was there without full combustion.
The Sherlock Holmes story, "Hound of the Baskervilles" by Conan Doyle, uses white phosphorus in the climax. I am not sure, but I don't think this is science fiction. White phosphorus glows.
How did people, using the chemoluminescence of white phosphorus, prevent it from bursting into flame?
Maybe white phosphorus is only slightly flammable. However, I know how deadly white phosphorus can be in war. So maybe the owner didn't mind the risk to the dog. However, there must have been some safety precautions when using white phosphorus.
1) Did the first matches, which used white phosphorus, glow green when exposed to air?
2) Did people using the chemoluminescence of white phosphoruse just keep it away from flame?
3) Did people mix white phosphorus with some inert substance that prevented flame?
 

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