When the charge on an isolated conductor is negative, its capacitance remains positive despite the negative charge. This is because capacitance is defined as the ratio of charge (Q) to voltage (V), and a negative charge will correspond with a negative voltage. However, since capacitance is a measure of the ability to store charge per unit voltage, it is always a positive value. Therefore, even with a negative charge, the capacitance does not become negative. The relationship between charge and voltage ensures that capacitance remains a positive quantity.