Infinite Square Well, finding Psi(x,t)

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SUMMARY

The discussion focuses on finding the time-dependent wave function ## \Psi(x,t) ## for a particle in an infinite square well with an initial wave function ## \Psi(x,0) = Ax(a-x) ##, where ## A = \sqrt{\dfrac{30}{a^5}} ## after normalization. The nth coefficients are determined using the equation ## c_n = \sqrt{\dfrac{2}{a}} \int_0^a \sin \left( \dfrac{n \pi x}{a}\right) \sqrt{\dfrac{30}{a^5}}x(a-x)dx ##, resulting in ## c_n = 0 ## for even n and ## c_n = \dfrac{8 \sqrt{15}}{(n \pi)^3} ## for odd n. The final expression for ## \Psi(x,t) ## incorporates a summation over odd n values, reflecting the time evolution of the wave function.

PREREQUISITES
  • Understanding of quantum mechanics concepts, particularly wave functions and normalization.
  • Familiarity with the infinite square well potential and its associated boundary conditions.
  • Knowledge of Fourier series and their application in quantum mechanics.
  • Proficiency in complex exponentials and their role in time evolution of quantum states.
NEXT STEPS
  • Study the derivation of energy eigenstates for the infinite square well potential.
  • Learn about the normalization process for wave functions in quantum mechanics.
  • Explore the concept of superposition of states and its implications for time evolution.
  • Investigate the role of Fourier series in solving quantum mechanical problems.
USEFUL FOR

Students and professionals in quantum mechanics, particularly those studying wave functions, normalization, and time evolution in quantum systems. This discussion is beneficial for anyone seeking to deepen their understanding of the infinite square well model.

Cogswell
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Homework Statement


A particle in the infinite square well has the initial wave function ## \Psi (x, 0) = Ax(a-x), (0 \le x \le a) ##, for some constant A. Outside the well, of course, ## \Psi = 0 ##.
Find ## \Psi (x,t)

2. Homework Equations :
Equation [1.0]:## \displaystyle c_n = \sqrt{\dfrac{2}{a}} \int_0^a \sin \left( \dfrac{n \pi x}{a}\right) \Psi (x,0)dx ##3. The answer (that is given):
First, determine A by normalising ## \Psi (x,0) ##

## \displaystyle 1 = \int_0^a | \Psi(x,t)|^2 dx##

Therefore ## A = \sqrt{\dfrac{30}{a^5}} ##

The nth coefficient is (Equation [1.0])

## \displaystyle c_n = \sqrt{\dfrac{2}{a}} \int_0^a \sin \left( \dfrac{n \pi x}{a}\right) \sqrt{\dfrac{30}{a^5}}x(a-x)dx ##

... skipped working...

## \displaystyle c_n = \dfrac{4 \sqrt{15}}{(n \pi)^3}[\cos(0) - \cos(n \pi)] ##

Therefore:

## c_n = 0 ## if n is even

## c_n = \dfrac{8 \sqrt{15}}{(n \pi)^3} ## if n is oddThus:

## \displaystyle \Psi (x,t) = \sqrt{\dfrac{30}{a}} \left( \dfrac{2}{a} \right) \sum \limits_{n=1, 3, 5...} \dfrac{1}{n^3} \sin \left( \dfrac{n \pi x}{a} \right) e^{(-in^2 \pi^2 \hbar t) / (2ma^2)} ##
4. The attempt at understanding it:

I get the normalisation part, and I get how they do the nth coefficient (hence I omitted the working) but I don't get why.

I thought all I had to do was normalise the ## \Psi (x,0)## and then add the time dependent factor to it, so shouldn't I get:

## \Psi (x,t) = \sqrt{\dfrac{30}{a^5}} x (a-x) \cdot e^{(-in^2 \pi^2 \hbar t) / (2ma^2)}##

Can someone explain this to me (in simple terms)?
 
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Hello, Cogswell.

If you look at your proposed solution, you can see a difficulty. What value of ##n## are you going to use in the time dependent factor?

Only the energy eigenstates ## \sin \left( \dfrac{n \pi x}{a}\right) ## evolve in time according to an exponential factor Exp##(-iE_n t/\hbar)##. Each energy eigenstate has its own time factor. So, the idea is to write the initial wavefunction as a superposition of energy eigenstates and then let each of those eigenstates evolve in time with its own time factor.
 

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